Kim, Tae Oh and Adachi, Motoaki and Okuyama, Kikuo and Seinfeld, John H. (1997) Experimental Measurement of Competitive Ion-Induced and Binary Homogeneous Nucleation in SO₂/H₂O/N₂ Mixtures. Aerosol Science and Technology, 26 (6). pp. 527-543. ISSN 0278-6826. doi:10.1080/02786829708965451. https://resolver.caltech.edu/CaltechAUTHORS:20230222-281718300.1
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Abstract
Alpha-ray radiolysis of SO₂/H₂O/N₂ gas mixtures is carried out to investigate the competitive processes of ion-induced and binary homogeneous nucleation in this system. Charged particles in the system are indicative of ion-induced nucleation and most likely involve water clusters. Charged particle neutralization was prevented by application of a dc electric field, therefore, uncharged particles in the system result from homogeneous nucleation. Hydroxyl (OH) radicals are generated by the a-ray radiolysis. Oxidation of SO₂ by OH radicals leads to sulfuric acid (H₂SO₄) vapor molecules and to subsequent binary homogeneous nucleation of H₂SO₄/H₂O. At increased SO₂ concentrations the contribution of binary homogeneous nucleation increases relative to that of ion-induced nucleation. Electrical mobility distributions of bipolar ions and nanometer-sized charged particles were measured with a cluster-differential mobility analyzer combined with a Faraday cup electrometer. In this system, ion-induced nucleation occurred preferentially on negative rather than positive ions.
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Alternate Title: | Experimental Measurement of Competitive Ion-Induced and Binary Homogeneous Nucleation in SO2/H2O/N2 Mixtures | ||||||||||
Additional Information: | This work was partly supported by Grant-in-Aid for Developmental Scientific Research (No. 07555235) and Grant-in-Aid for International Scientific Research (Joint Research) (No. 08044151) from the Ministry of Education, Culture and Science, and Proposal-Based Advanced Industrial Technology R&D Program of NEDO (No. C-1111) (KO). Acknowledgment is also made to National Science Foundation grant ATM9307603 (IHS). | ||||||||||
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Issue or Number: | 6 | ||||||||||
DOI: | 10.1080/02786829708965451 | ||||||||||
Record Number: | CaltechAUTHORS:20230222-281718300.1 | ||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20230222-281718300.1 | ||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||
ID Code: | 119474 | ||||||||||
Collection: | CaltechAUTHORS | ||||||||||
Deposited By: | Tony Diaz | ||||||||||
Deposited On: | 22 Feb 2023 23:50 | ||||||||||
Last Modified: | 22 Feb 2023 23:50 |
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