Meng, Zhaoyue and Seinfeld, John H. and Saxena, Pradeep (1995) Gas/Aerosol Distribution of Formic and Acetic Acids. Aerosol Science and Technology, 23 (4). pp. 561-578. ISSN 0278-6826. doi:10.1080/02786829508965338. https://resolver.caltech.edu/CaltechAUTHORS:20230226-660977600.5
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Abstract
Data and correlations for evaluating the gas/aerosol equilibrium of formic and acetic acids are developed. The species considered include HCOOH(g), CH₃COOH(g), HCOOH(aq), CH₃COOH(aq), HCOO⁻, CH₃COO⁻, HCOONa(s), CH₃COONa(s), HCOOK(s), (HCOO)₂Ca(s), and (CH₃COO)₂Ca(s). Based on available thermodynamic data, we show that the gas /aerosol distribution of formic and acetic acids is strongly on the gas-phase side for typical sulfate/ nitrate / ammonium / sodium / chloride / water aerosols and that dissolved formate and acetate have negligible effect on the gas/aerosol equilibrium of the other components.
Item Type: | Article | ||||||
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Additional Information: | This work was supported by the Electric Power Research Institute under agreement RP3189-03. | ||||||
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Issue or Number: | 4 | ||||||
DOI: | 10.1080/02786829508965338 | ||||||
Record Number: | CaltechAUTHORS:20230226-660977600.5 | ||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20230226-660977600.5 | ||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
ID Code: | 119506 | ||||||
Collection: | CaltechAUTHORS | ||||||
Deposited By: | Tony Diaz | ||||||
Deposited On: | 28 Feb 2023 17:03 | ||||||
Last Modified: | 28 Feb 2023 17:03 |
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