Marcus, R. A. (1952) Lifetimes of active molecules. II. Journal of Chemical Physics, 20 (3). pp. 355-359. ISSN 0021-9606. https://resolver.caltech.edu/CaltechAUTHORS:MARjcp52c
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Abstract
Experimental data on the atomic cracking of propyl radicals and on the deuterization of methyl radicals are compared with some theoretical calculations. With the aid of some assumptions concerning intramolecular energy transfer in the dissociating molecules involved in these and other reactions and concerning the corresponding activated complexes, data on a number of free radical reactions are correlated.
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| Additional Information: | © 1952 American Institute of Physics. Received August 14, 1951. This work was financially assisted by the ONR, Contract No. N8onr-77900. I should like to acknowledge a number of very helpful discussions with Professor O.K. Rice. | ||||||||||||
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| Issue or Number: | 3 | ||||||||||||
| Record Number: | CaltechAUTHORS:MARjcp52c | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:MARjcp52c | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 12386 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Tony Diaz | ||||||||||||
| Deposited On: | 03 Dec 2008 23:36 | ||||||||||||
| Last Modified: | 22 Nov 2019 09:58 |
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