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Ping-Pong Electron Transfer through DNA

Elias, Benjamin and Genereux, Joseph C. and Barton, Jacqueline K. (2008) Ping-Pong Electron Transfer through DNA. Angewandte Chemie International Edition, 47 (47). pp. 9067-9070. ISSN 1433-7851. PMCID PMC2748353. https://resolver.caltech.edu/CaltechAUTHORS:ELIac08

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Abstract

Herein we describe a novel Ir system that is able to promote the reduction of pyrimidine bases from a distance without the presence of an external quencher. Instead, DNA-mediated ET is triggered by DNA-mediated HT. Thus, photoactivation of these Ir assemblies results in both a forward and a reverse pattern for charge migration, which we term ping-pong electron transfer through DNA (Scheme 1).


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/anie.200803556DOIArticle
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2748353/PubMed CentralArticle
ORCID:
AuthorORCID
Elias, Benjamin0000-0001-5037-3313
Genereux, Joseph C.0000-0002-5093-7710
Barton, Jacqueline K.0000-0001-9883-1600
Additional Information:© 2008 Wiley-VCH. Received: July 22, 2008. Published online: October 16, 2008. This work was supported by the NIH (GM49216).
Funders:
Funding AgencyGrant Number
NIHGM49216
Subject Keywords:charge transport; DNA damage; iridium
Issue or Number:47
PubMed Central ID:PMC2748353
Record Number:CaltechAUTHORS:ELIac08
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:ELIac08
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:12565
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:12 Dec 2008 23:14
Last Modified:14 Feb 2020 17:43

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