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Synthesis and Reactivity of Iridium(III) Dihydrido Aminocarbenes

Whited, Michael T. and Grubbs, Robert H. (2008) Synthesis and Reactivity of Iridium(III) Dihydrido Aminocarbenes. Organometallics, 27 (22). pp. 5737-5740. ISSN 0276-7333. http://resolver.caltech.edu/CaltechAUTHORS:WHIo08

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Abstract

Iridium complexes supported by the PNP amidophosphine scaffold (PNP = [N(2-PiPr2-4-Me-C6H3)2]−) perform the selective double C−H activation of methyl amines to produce iridium(III) dihydrido aminocarbenes. The reactivity of these complexes is presented and contrasted with that observed for the previously reported iridium(I) alkoxycarbenes.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/om8009365DOIArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2008 American Chemical Society. Received September 26, 2008. Publication Date (Web): October 28, 2008. We gratefully acknowledge the Moore Foundation (fellowship to M.T.W.) and BP (MC2 program) for financial support. Larry Henling provided crystallographic assistance. Supporting Information: Text giving detailed experimental procedures and characterization data and CIF files giving crystallographic details for compounds 2anti, 4, and 6. This material is available free of charge via the Internet at http://pubs.acs.org.
Funders:
Funding AgencyGrant Number
Gordon and Betty Moore FoundationUNSPECIFIED
BP MC2 programUNSPECIFIED
Record Number:CaltechAUTHORS:WHIo08
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:WHIo08
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:12674
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:19 Dec 2008 04:45
Last Modified:08 Dec 2016 22:44

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