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Phosphido Pincer Complexes of Palladium as New Efficient Catalysts for Allylation of Aldehydes

Mazzeo, Mina and Lamberti, Marina and Massa, Antonio and Scettri, Arrigo and Pellecchia, Claudio and Peters, Jonas C. (2008) Phosphido Pincer Complexes of Palladium as New Efficient Catalysts for Allylation of Aldehydes. Organometallics, 27 (22). pp. 5741-5743. ISSN 0276-7333.

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Palladium complexes supported by tridentate phosphido diphosphine ligands (P(o-C6H4PR2)2: 1, R = iPr; 2, R = Ph) have been synthesized, characterized, and tested as catalysts for the electrophilic allylation of aldehydes. The palladium complex 2 resulted in an interesting catalyst for electrophilic allylation in the presence of allyltributyltin, giving good yields under very mild reaction conditions and even in the absence of the solvent.

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Peters, Jonas C.0000-0002-6610-4414
Additional Information:Copyright © 2008 American Chemical Society. Received September 3, 2008. Publication Date (Web): October 22, 2008. We thank Matt T. Whited for assistance with crystallographic studies. Supporting Information: Text, figures, and tables giving experimental procedures for the synthesis and characterization data of compounds 1 and 2 and X-ray structural solution and crystal data for 1; X-ray data for 1 are also given as a CIF file. This material is available free of charge via the Internet at
Issue or Number:22
Record Number:CaltechAUTHORS:MAZo08
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:12675
Deposited By: Archive Administrator
Deposited On:19 Dec 2008 05:11
Last Modified:26 Nov 2019 11:15

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