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Radial Differential Mobility Analyzer for One Nanometer Particle Classification

Brunelli, N. A. and Flagan, R. C. and Giapis, K. P. (2008) Radial Differential Mobility Analyzer for One Nanometer Particle Classification. Aerosol Science and Technology, 43 (1). pp. 53-59. ISSN 0278-6826. doi:10.1080/02786820802464302. https://resolver.caltech.edu/CaltechAUTHORS:BRUast09

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Abstract

We present details on the design, construction, and calibration of a radial differential mobility analyzer suitable for sizing aerosol nanoparticles with mobility diameters as small as one nanometer. Design improvements targeted decreasing the residence time with a concomitant reduction in particle agglomeration and diffusional losses to walls. Calibration was performed using aerosolized monodisperse molecular ions. Instrument resolution was found to increase with applied voltage as V^1/2, indicating that diffusion is broadening the transfer function and reaching a value of ~7 for the largest molecular ion measured (mobility diameter of 1.47 nm). The mobilities of three molecular ions in the tetra-alkyl ammonium halide homologous series are also reported.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1080/02786820802464302DOIArticle
ORCID:
AuthorORCID
Flagan, R. C.0000-0001-5690-770X
Giapis, K. P.0000-0002-7393-298X
Additional Information:© 2009 Copyright American Association for Aerosol Research. Received 10 June 2008; accepted 9 September 2008. This work was partially supported by the Jacobs Institute for Molecular Engineering and Medicine at Caltech. An NSF graduate fellowship to NAB is also acknowledged.
Funders:
Funding AgencyGrant Number
Caltech Jacobs Institute for Molecular Engineering for MedicineUNSPECIFIED
NSF Graduate Research FellowshipUNSPECIFIED
Issue or Number:1
DOI:10.1080/02786820802464302
Record Number:CaltechAUTHORS:BRUast09
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:BRUast09
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:13248
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:05 Feb 2009 07:13
Last Modified:08 Nov 2021 22:36

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