CaltechAUTHORS
  A Caltech Library Service

Oxidative aromatization of olefins with dioxygen catalyzed by palladium trifluoroacetate

Bercaw, John E. and Hazari, Nilay and Labinger, Jay A. (2008) Oxidative aromatization of olefins with dioxygen catalyzed by palladium trifluoroacetate. Journal of Organic Chemistry, 73 (21). pp. 8654-8657. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:BERjoc08

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:BERjoc08

Abstract

Molecular oxygen can replace sacrificial olefins as the hydrogen acceptor in the palladium trifluoroacetate catalyzed dehydrogenation of cyclohexene and related cyclic olefins into aromatics. One of the major drawbacks of the homogeneous system is the tendency of the palladium trifluoroacetate to precipitate as palladium(0) at elevated temperatures. The use of better ligands affords catalysts that can operate at higher temperatures, although they are less reactive than palladium trifluoroacetate.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/jo8016296DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jo8016296PublisherArticle
ORCID:
AuthorORCID
Labinger, Jay A.0000-0002-1942-9232
Additional Information:© 2008 American Chemical Society. Received July 23, 2008. We thank Professor Shannon Stahl for useful discussions. This work was supported by BP through the MC2 program.
Funders:
Funding AgencyGrant Number
BP MC2 programUNSPECIFIED
Subject Keywords:H bond activation; molecular-oxygen; organic-chemicals; pincer complexes; dehydrogenation; PD; mechanism
Issue or Number:21
Record Number:CaltechAUTHORS:BERjoc08
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:BERjoc08
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:13572
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:08 May 2009 21:41
Last Modified:03 Oct 2019 00:40

Repository Staff Only: item control page