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Cation field strength effects on high pressure aluminosilicate glass structure: Multinuclear NMR and La XAFS results

Kelsey, Kimberly E. and Stebbins, Jonathan F. and Singer, David M. and Brown, Gordon E., Jr. and Mosenfelder, Jed L. and Asimow, Paul D. (2009) Cation field strength effects on high pressure aluminosilicate glass structure: Multinuclear NMR and La XAFS results. Geochimica et Cosmochimica Acta, 73 (13). pp. 3914-3933. ISSN 0016-7037.

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We examined aluminosilicate glasses containing a variety of network modifying to intermediate cations (Li, La, Sc, and Fe), quenched from melts at 1 atm to 8 GPa, to further investigate the role of cation field strength in Al coordination changes and densification. ^(27)Al Nuclear Magnetic Resonance Spectroscopy (NMR) reveals that the mean Al coordination increases with increasing pressure in the Li-containing glasses, which can be explained by a linear dependence of fractional change in Al coordination number on cation field strengths in similar K-, Na-, and Ca-containing aluminosilicate glasses (K < Na < Li < Ca). Measured recovered densities follow a similar linear trend. In contrast, the La-containing glasses have significantly lower mean Al coordination numbers at given pressures than the cation field strength of La and glass density would predict. La L_3 X-ray absorption fine structure (XAFS) spectroscopy results indicate a significant increase with pressure in average La–O bond distances, suggesting that La and Al may be “competing” for higher coordinated sites and hence that both play a significant role in the densification of these glasses, especially in the lower pressure range. However, in Na aluminosilicate glasses with small amounts of Sc, ^(45)Sc NMR reveals only modest Sc coordination changes, which do not seem to significantly affect the mean Al coordination values. For a Li aluminosilicate glass, ^(17)O MAS and multiple quantum magic angle spinning (3QMAS) NMR data are consistent with generation of more highly coordinated Al at the expense of non-bridging oxygen (NBO), whereas La aluminosilicate glasses have roughly constant O environments, even up to 8 GPa. Finally, we demonstrate that useful ^(23)Na and ^(27)Al MAS NMR spectra can be collected for Ca–Na aluminosilicate glasses containing up to 5 wt.% Fe oxide. We discuss the types of structural changes that may accompany density increases with pressure and how these structural changes are affected by the presence of different cations.

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Asimow, Paul D.0000-0001-6025-8925
Additional Information:Copyright © 2009 Elsevier. Received 18 September 2008; accepted 30 March 2009. Associate editor: Michael Toplis. Available online 14 April 2009. We are grateful to Bob Jones for microprobe analyses, to Namjun Kim for help with the ^(45)Sc NMR, to Sarah Gaudio (University of California, Davis) for assistance with density measurements, to François Farges (Muséum National d’Histoire Naturelle, Paris) for useful discussion about the La XAFS, and to J. Puglisi and C. Liu for access to the 18.8 T NMR spectrometer at the Stanford Magnetic Resonance Laboratory. We also thank John Bargar, Joe Rogers, and the SSRL staff for continuing beamline support at the Stanford Synchrotron Radiation Laboratory. SSRL is a national user facility operated by Stanford University on behalf of the U.S. Department of Energy, Office of Basic Energy Sciences, and is also supported by the DOE Office of Biological and Environmental Research, and by the National Institutes of Health, National Center for Research Resources, Biomedical Technology Program. We acknowledge the support of the NSF for funding under Grant Nos. EAR-0408410 (Stebbins), CHE-0431425 (Brown), and OCE-0550216 (Asimow), and Associate Editor Mike Toplis, as well as S.K. Lee and two anonymous reviewers for helpful comments on the original version of this paper.
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Department of EnergyUNSPECIFIED
Issue or Number:13
Record Number:CaltechAUTHORS:20090904-104213330
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Official Citation:Kimberly E. Kelsey, Jonathan F. Stebbins, David M. Singer, Gordon E. Brown Jr., Jed L. Mosenfelder, Paul D. Asimow, Cation field strength effects on high pressure aluminosilicate glass structure: Multinuclear NMR and La XAFS results, Geochimica et Cosmochimica Acta, Volume 73, Issue 13, 1 July 2009, Pages 3914-3933, ISSN 0016-7037, DOI: 10.1016/j.gca.2009.03.040. (
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:15611
Deposited By: George Porter
Deposited On:22 Sep 2009 18:12
Last Modified:03 Oct 2019 01:00

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