Møller, Chr. and Plesset, M. S. (1934) Note on an Approximation Treatment for Many-Electron Systems. Physical Review, 46 (7). pp. 618-622. ISSN 0031-899X. doi:10.1103/PhysRev.46.618. https://resolver.caltech.edu/CaltechAUTHORS:MOLpr34
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Abstract
A perturbation theory is developed for treating a system of n electrons in which the Hartree-Fock solution appears as the zero-order approximation. It is shown by this development that the first order correction for the energy and the charge density of the system is zero. The expression for the second-order correction for the energy greatly simplifies because of the special property of the zero-order solution. It is pointed out that the development of the higher approximation involves only calculations based on a definite one-body problem.
Item Type: | Article | ||||||
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Additional Information: | ©1934 The American Physical Society Received 14 July 1934 | ||||||
Issue or Number: | 7 | ||||||
DOI: | 10.1103/PhysRev.46.618 | ||||||
Record Number: | CaltechAUTHORS:MOLpr34 | ||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:MOLpr34 | ||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
ID Code: | 1753 | ||||||
Collection: | CaltechAUTHORS | ||||||
Deposited By: | Archive Administrator | ||||||
Deposited On: | 16 Feb 2006 | ||||||
Last Modified: | 08 Nov 2021 19:42 |
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