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Note on an Approximation Treatment for Many-Electron Systems

Møller, Chr. and Plesset, M. S. (1934) Note on an Approximation Treatment for Many-Electron Systems. Physical Review, 46 (7). pp. 618-622. ISSN 0031-899X. http://resolver.caltech.edu/CaltechAUTHORS:MOLpr34

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Abstract

A perturbation theory is developed for treating a system of n electrons in which the Hartree-Fock solution appears as the zero-order approximation. It is shown by this development that the first order correction for the energy and the charge density of the system is zero. The expression for the second-order correction for the energy greatly simplifies because of the special property of the zero-order solution. It is pointed out that the development of the higher approximation involves only calculations based on a definite one-body problem.


Item Type:Article
Additional Information:©1934 The American Physical Society Received 14 July 1934
Record Number:CaltechAUTHORS:MOLpr34
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:MOLpr34
Alternative URL:http://dx.doi.org/10.1103/PhysRev.46.618
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:1753
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:16 Feb 2006
Last Modified:26 Dec 2012 08:45

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