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Tris(hydroxypropyl)phosphine Oxide: A Chiral Three-Dimensional Material with Nonlinear Optical Properties

Durrell, Alec C. and Gray, Harry B. and Hazari, Nilay and Incarvito, Christopher D. and Liu, Jian and Yan, Elsa C. Y. (2010) Tris(hydroxypropyl)phosphine Oxide: A Chiral Three-Dimensional Material with Nonlinear Optical Properties. Crystal Growth and Design, 10 (4). pp. 1482-1485. ISSN 1528-7483. https://resolver.caltech.edu/CaltechAUTHORS:20100517-091141484

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Abstract

The achiral C_(3v) organic phosphine tris(hydroxypropyl)phosphine oxide (1) crystallizes in the unusual chiral hexagonal space group P6_3. The structure is highly ordered because each phosphine oxide moiety forms three hydrogen bonds with adjacent hydroxy groups from three different molecules. The properties of the crystals and the presence of hydrogen bonding interactions were investigated using single crystal Raman spectroscopy. The crystals show nonlinear optical properties and are capable of efficient second harmonic generation.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/cg1001286 DOIArticle
http://pubs.acs.org/doi/abs/10.1021/cg1001286PublisherArticle
ORCID:
AuthorORCID
Gray, Harry B.0000-0002-7937-7876
Additional Information:© 2010 American Chemical Society. Received January 27, 2010. Publication Date (Web): March 17, 2010. We thank Larry Henling for assistance with face indexing the crystal and George Rossman for assistance with single crystal Raman spectroscopy. This research was supported in part by the Starter Grant Award from the Spectroscopy Society of Pittsburgh (to E. C.Y.Y.) and the NSF Center for Chemical Innovation (CCI Powering the Plant, Grants CHE-0802907 and CHE-0947829 to H.B.G.).
Group:CCI Solar Fuels
Funders:
Funding AgencyGrant Number
Spectroscopy Society of Pittsburgh UNSPECIFIED
NSFCHE-0802907
NSFCHE-0947829
Issue or Number:4
Record Number:CaltechAUTHORS:20100517-091141484
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20100517-091141484
Official Citation:1.Tris(hydroxypropyl)phosphine Oxide: A Chiral Three-Dimensional Material with Nonlinear Optical Properties Alec C. Durrell, Harry B. Gray, Nilay Hazari, Christopher D. Incarvito, Jian Liu, Elsa C. Y. Yan Crystal Growth & Design 2010 10 (4), 1482-1485
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:18317
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:07 Jun 2010 19:19
Last Modified:22 Nov 2019 09:58

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