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NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

Fulmer, Gregory R. and Miller, Alexander J. M. and Sherden, Nathaniel H. and Gottlieb, Hugo E. and Nudelman, Abraham and Stoltz, Brian M. and Bercaw, John E. and Goldberg, Karen I. (2010) NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist. Organometallics, 29 (9). pp. 2176-2179. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20100527-094834306

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Abstract

Tables of ^1H and ^(13)C NMR chemical shifts have been compiled for common organic compounds often used as reagents or found as products or contaminants in deuterated organic solvents. Building upon the work of Gottlieb, Kotlyar, and Nudelman in the Journal of Organic Chemistry, signals for common impurities are now reported in additional NMR solvents (tetrahydrofuran-d_8, toluene-d_8, dichloromethane-d_2, chlorobenzene-d_5, and 2,2,2-trifluoroethanol-d_3) which are frequently used in organometallic laboratories. Chemical shifts for other organics which are often used as reagents or internal standards or are found as products in organometallic chemistry are also reported for all the listed solvents.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/om100106eDOIArticle
http://pubs.acs.org/doi/abs/10.1021/om100106ePublisherArticle
ORCID:
AuthorORCID
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2010 American Chemical Society. Published In Issue May 10, 2010. Received February 11, 2010. Publication Date (Web): April 16, 2010. Article ASAP April 16, 2010. G.R.F. and K.I.G. thank the Department of Energy (Contract No. DE-FG02-06ER15765) for support. A.J.M.M. and J.E.B. thank the Moore Foundation for support. N.H.S. and B.M.S. thank Abbott Laboratories, Amgen, Merck, Bristol-Myers Squibb, Boehringer Ingelheim, the Gordon and Betty Moore Foundation, and Caltech for financial support.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-FG02-06ER15765
Gordon and Betty Moore FoundationUNSPECIFIED
Abbott LaboratoriesUNSPECIFIED
AmgenUNSPECIFIED
MerckUNSPECIFIED
Bristol-Myers SquibbUNSPECIFIED
Boehringer IngelheimUNSPECIFIED
CaltechUNSPECIFIED
Issue or Number:9
Record Number:CaltechAUTHORS:20100527-094834306
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20100527-094834306
Official Citation:NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist Gregory R. Fulmer, Alexander J. M. Miller, Nathaniel H. Sherden, Hugo E. Gottlieb, Abraham Nudelman, Brian M. Stoltz, John E. Bercaw, Karen I. Goldberg Organometallics 2010 29 (9), 2176-2179
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:18475
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:27 May 2010 17:28
Last Modified:03 Oct 2019 01:43

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