CaltechAUTHORS
  A Caltech Library Service

Synthesis and C−C Coupling Reactivity of a Dinuclear Ni^I−Ni^I Complex Supported by a Terphenyl Diphosphine

Velian, Alexandra and Lin, Sibo and Miller, Alexander J. M. and Day, Michael W. and Agapie, Theodor (2010) Synthesis and C−C Coupling Reactivity of a Dinuclear Ni^I−Ni^I Complex Supported by a Terphenyl Diphosphine. Journal of the American Chemical Society, 132 (18). pp. 6296-6297. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20100601-111503988

[img]
Preview
PDF - Supplemental Material
See Usage Policy.

2438Kb
[img] Crystallographic Info File (CIF) - Supplemental Material
See Usage Policy.

23Kb
[img] Crystallographic Info File (CIF) - Supplemental Material
See Usage Policy.

19Kb
[img] Crystallographic Info File (CIF) - Supplemental Material
See Usage Policy.

26Kb
[img] Crystallographic Info File (CIF) - Supplemental Material
See Usage Policy.

13Kb

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20100601-111503988

Abstract

Mono- and bimetallic complexes of nickel supported by a terphenyl diphosphine have been synthesized. The reported complexes show diverse metal−arene interactions in the solid state. Reactions of an o,o′-biphenyldiyl dinickel complex with CO and dichloroalkanes lead to fluorene derivatives, indicating the formation of carbon−carbon bonds at a bimetallic moiety.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja101699aDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja101699aPublisherArticle
ORCID:
AuthorORCID
Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2010 American Chemical Society. Received March 4, 2010. We thank Lawrence M. Henling for crystallographic assistance. We are grateful to Caltech, bp, NSF GRFP (S.L.), and the Caltech SURF Program (A.V.) for funding. The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU Award to Caltech (CHE-0639094).
Funders:
Funding AgencyGrant Number
CaltechUNSPECIFIED
British PetroleumUNSPECIFIED
NSF Graduate Research FellowshipUNSPECIFIED
Caltech Summer Undergraduate Research Fellowship (SURF)UNSPECIFIED
Issue or Number:18
Record Number:CaltechAUTHORS:20100601-111503988
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20100601-111503988
Official Citation:Synthesis and C−C Coupling Reactivity of a Dinuclear NiI−NiI Complex Supported by a Terphenyl Diphosphine Alexandra Velian, Sibo Lin, Alexander J. M. Miller, Michael W. Day, Theodor Agapie Journal of the American Chemical Society 2010 132 (18), 6296-6297
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:18504
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:02 Jun 2010 15:47
Last Modified:03 Oct 2019 01:43

Repository Staff Only: item control page