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Access to Well-Defined Ruthenium(I) and Osmium(I) Metalloradicals

Takaoka, Ayumi and Gerber, Laura C. H. and Peters, Jonas C. (2010) Access to Well-Defined Ruthenium(I) and Osmium(I) Metalloradicals. Angewandte Chemie International Edition, 49 (24). pp. 4088-4091. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20100709-101044545

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Abstract

Radically complex: Well-defined mononuclear RuI and OsI complexes (see scheme) have metalloradical character, as indicated by EPR spectroscopy and DFT calculations. The Ru^I and Os^I metalloradicals exhibit both one-electron and two-electron redox reactivity. The latter process affords unusual imido complexes with substantial radical character on the {ArN} moiety.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/anie.201001199 DOIUNSPECIFIED
http://www3.interscience.wiley.com/journal/123424719/abstract?CRETRY=1&SRETRY=0PublisherUNSPECIFIED
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2010 Wiley. Received: 26 February 2010; Published online: May 7, 2010. This work was supported by the NIH (GM070757). Samantha MacMillan and Dr. Peter Mller are acknowledged for crystallographic assistance. The NSF is acknowledged for use of instruments at the MIT DCIF (CHE-9808061, DBI-97299592).
Funders:
Funding AgencyGrant Number
NIHGM070757
NSFCHE-9808061
NSFDBI-97299592
Subject Keywords:group transfer; imido ligands; imidyl ligands; metalloradicals; nitrogen complexes
Issue or Number:24
Record Number:CaltechAUTHORS:20100709-101044545
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20100709-101044545
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:18957
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:09 Jul 2010 22:54
Last Modified:26 Nov 2019 11:15

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