Darvish, Davis S. and Atwater, Harry A. (2009) Modeling, synthesis, and characterization of thin film copper oxide for solar cells. In: 34th IEEE Photovoltaic Specialists Conference. IEEE , New York, pp. 1228-1232. ISBN 978-1-4244-2949-3. https://resolver.caltech.edu/CaltechAUTHORS:20100816-105436956
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Abstract
The modeling, growth, and characterization of Copper Oxide thin films for solar cell applications are reported. Cu_2O has several attractive properties which include its direct band gap (Eg=2.17 eV) for use in photoelectrolysis of water and use in tandem multi-junction cells. Detailed balance calculations predict efficiencies on the order of 20% while Cu_2O cells have yet to even pass 2% efficiency. The device physics model reveals that defects, particularly at the heterojunction interface, are the main reason for lowered efficiencies. Epitaxial Cu_2O (100) thin films on MgO are fabricated using RF Oxygen plasma MBE. The films are quite smooth and showed mobilites in the range of 10-100 cm^2/V*sec and carrier concentrations in the range of 10^(14)-10^(17). Finally, the epitaxial growth of Cu_2O on a MgO template is demonstrated.
Item Type: | Book Section | |||||||||
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Additional Information: | © 2009 IEEE. We acknowledge financial support from U.S. Department of Energy under grant DE-FG36-08G018006, and the Caltech Center for Sustainable Energy Research. We thank Dr. Matthew Dicken, Greg Kimball, and Carrie Hofmann for engaging discussions and assistance. | |||||||||
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DOI: | 10.1109/PVSC.2009.5411394 | |||||||||
Record Number: | CaltechAUTHORS:20100816-105436956 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20100816-105436956 | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 19438 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Tony Diaz | |||||||||
Deposited On: | 16 Aug 2010 18:11 | |||||||||
Last Modified: | 08 Nov 2021 23:52 |
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