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Lead-tellurium oxysalts from Otto Mountain near Baker, California: IV. Markcooperite, Pb(UO_2)Te^(6+)O_6, the first natural uranyl tellurate

Kampf, Anthony R. and Mills, Stuart J. and Housley, Robert M. and Marty, Joseph and Thorne, Brent (2010) Lead-tellurium oxysalts from Otto Mountain near Baker, California: IV. Markcooperite, Pb(UO_2)Te^(6+)O_6, the first natural uranyl tellurate. American Mineralogist, 95 (10). pp. 1554-1559. ISSN 0003-004X. http://resolver.caltech.edu/CaltechAUTHORS:20101028-083030272

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Abstract

Markcooperite, Pb_2(UO_2)Te^(6+)O_6, is a new tellurate from Otto Mountain near Baker, California, named in honor of Mark A. Cooper of the University of Manitoba for his contributions to mineralogy. The new mineral occurs on fracture surfaces and in small vugs in brecciated quartz veins. Markcooperite is directly associated with bromian chlorargyrite, iodargyrite, khinite-4O, wulfenite, and four other new tellurates: housleyite, thorneite, ottoite, and timroseite. Various other secondary minerals occur in the veins, including two other new secondary tellurium minerals: paratimroseite and telluroperite. Markcooperite is monoclinic, space group P2_1/c, a = 5.722(2), b = 7.7478(2), c = 7.889(2) Å, β = 90.833(5)°, V = 349.7(2) Å^3, and Z = 2. It occurs as pseudotetragonal prisms to 0.2 mm with the forms {100} and {011} and as botryoidal intergrowths to 0.3 mm in diameter; no twinning was observed. Markcooperite is orange and transparent, with a light orange streak and adamantine luster, and is non-fluorescent. Mohs hardness is estimated at 3. The mineral is brittle, with an irregular fracture and perfect {100} cleavage. The calculated density is 8.496 g/cm3 based on the empirical formula. Markcooperite is biaxial (+), with indices of refraction α= 2.11, β = 2.12, γ= 2.29 calculated using the Gladstone-Dale relationship, measured α-β birefringence of 0.01 and measured 2V of 30(5)°. The optical orientation is X = c, Y = b, Z = a. The mineral is slightly pleochroic in shades of orange, with absorption: X > Y = Z. No dispersion was observed. Electron microprobe analysis provided PbO 50.07, TeO_3 22.64, UO_3 25.01, Cl 0.03, O≡Cl –0.01, total 97.74 wt%; the empirical formula (based on O+Cl = 8) is Pb_(2.05)U_(0.80)Te^(6+)_(1.18)O_(7.99)Cl_(0.01). The strongest powder X-ray diffraction lines are [d_(obs) in Å (hkl) I]: 3.235 (120, 102, 1[overbar]02) 100, 2.873 (200) 40, 2.985 (1[overbar]21, 112, 121) 37, 2.774 (022) 30, 3.501 (021, 012) 29, 2.220 (221, 2[overbar]21, 212) 23, 1.990 (222, 2[overbar]22) 21, and 1.715 (320) 22. The crystal structure (R_1 = 0.052) is based on sheets of corner-sharing uranyl square bipyramids and tellurate octahedra, with Pb atoms between the sheets. Markcooperite is the first compound to show Te^(6+) substitution for U^(6+) within the same crystallographic site. Markcooperite is structurally related to synthetic Pb(UO_2)O_2.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.2138/am.2010.3513 DOIUNSPECIFIED
http://ammin.geoscienceworld.org/cgi/content/abstract/95/10/1554PublisherUNSPECIFIED
Additional Information:© 2010 Mineralogical Society of America. Manuscript received January 28, 2010. Manuscript accepted May 5, 2010. Manuscript handled by G. Diego Gatta. We thank Associate Editor G. Diego Gatta, referee Daniela Pinto, Technical Editor Ron Peterson, and two anonymous reviewers for helpful comments on the manuscript. The EMP analyses were supported by a grant to the California Institute of Technology from the Northern California Mineralogical Association. The remainder of this study was funded by the John Jago Trelawney Endowment to the Mineral Sciences Department of the Natural History Museum of Los Angeles County.
Funders:
Funding AgencyGrant Number
Northern California Mineralogical Association UNSPECIFIED
John Jago Trelawney Endowment UNSPECIFIED
Subject Keywords:Markcooperite; new mineral; tellurate; uranyl; crystal structure; Otto Mountain; California
Record Number:CaltechAUTHORS:20101028-083030272
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20101028-083030272
Official Citation:Kampf, A. R., S. J. Mills, et al. (2010). "Lead-tellurium oxysalts from Otto Mountain near Baker, California: IV. Markcooperite, Pb(UO2)Te6+O6, the first natural uranyl tellurate." American Mineralogist 95(10): 1554-1559. DOI: 10.2138/am.2010.3513
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:20573
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:23 Nov 2010 19:54
Last Modified:26 Dec 2012 12:34

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