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Facile Synthesis of Effcient and Selective Ruthenium Olefin Metathesis Catalysts with Sulfonate and Phosphate Ligands

Teo, Peili and Grubbs, Robert H. (2010) Facile Synthesis of Effcient and Selective Ruthenium Olefin Metathesis Catalysts with Sulfonate and Phosphate Ligands. Organometallics, 29 (22). pp. 6045-6050. ISSN 0276-7333. http://resolver.caltech.edu/CaltechAUTHORS:20110201-145319110

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Abstract

A series of novel, air-stable ruthenium NHC catalysts with sulfonate and phosphate anions have been prepared easily in one pot at high yields using commercially available precursors. The catalysts were found to be effective for ring-opening metathesis polymerization, ring-closing metathesis, and cross-metathesis. The catalysts showed higher cis-selectivity in olefin cross-metathesis reactions as compared to earlier known ruthenium-based olefin metathesis catalysts, with allylbenzene and cis-1,4-diacetoxybutene as substrates.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/om1007924 DOIArticle
http://pubs.acs.org/doi/full/10.1021/om1007924PublisherArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2010 American Chemical Society. Received August 14, 2010. Publication Date (Web): October 25, 2010. We thank K. Endo for helpful discussions. P.T. is grateful to A*STAR Singapore for a postdoctoral fellowship and NSF for a research grant.
Errata:Title has typographical error ("effcient") included in published version.
Funders:
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Agency for Science, Technology and Research (A*STAR)UNSPECIFIED
NSFUNSPECIFIED
Record Number:CaltechAUTHORS:20110201-145319110
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20110201-145319110
Official Citation:Facile Synthesis of Effcient and Selective Ruthenium Olefin Metathesis Catalysts with Sulfonate and Phosphate Ligands Peili Teo, Robert H. Grubbs Organometallics 2010 29 (22), 6045-6050
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:21956
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:14 Feb 2011 18:29
Last Modified:08 Dec 2016 21:57

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