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Insights Into the Carbene-Initiated Aggregation of [Fe(cot)_2]

Lavallo, Vincent and El-Batta, Amer and Bertrand, Guy and Grubbs, Robert H. (2011) Insights Into the Carbene-Initiated Aggregation of [Fe(cot)_2]. Angewandte Chemie International Edition, 50 (1). pp. 268-271. ISSN 1433-7851. PMCID PMC3057625. https://resolver.caltech.edu/CaltechAUTHORS:20110224-100557609

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Abstract

Stable carbenes react with [Fe(cot)_2] in very different ways. Whereas the classical N-heterocyclic carbenes induce the formation of tetra- and trimetallic iron clusters, abnormal NHCs and carbocyclic carbenes (BACs) form mono- and bimetallic iron complexes. Cyclic (alkyl)(amino)carbenes (CAACs) react with [Fe(cot)_2] in a completely different manner, namely through outersphere [4+1] cycloaddition.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/anie.201005212DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/anie.201005212/abstractPublisherArticle
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3057625/PubMed CentralArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: August 20, 2010. Article first published online: 25 Nov. 2010. We gratefully acknowledge financial support from the NIH (grants 5R01 GM 31332 and R01 GM 68825, and N.R.S.A. fellowship for V.L. This publication was based on work supported by Award No. K-C1-019-12 made by King Abdullah University of Science and Technology (KAUST). The support of King Fahd University of Petroleum and Minerals (KFUPM) is also highly appreciated. We thank L. M. Henling and M. W. Day (California Institute of Technology) for X-ray crystallographic analysis. The Bruker KAPPA APEX II X-ray diffractometer was purchased via an NSF Chemistry Research Instrumentation and Facilities: Multi-User award to the California Institute of Technology, CHE-0639094.
Funders:
Funding AgencyGrant Number
NIH5R01 GM 31332
NIHR01 GM 68825
King Fahd University of Petroleum and Minerals (KFUPM)UNSPECIFIED
National Research Service Award (NRSA) Fellowship UNSPECIFIED
NSFCHE-0639094
King Abdullah University of Science and Technology (KAUST)K-C1-019-12
Subject Keywords:carbenes; homogeneous catalysis; iron complexes; organometallic compounds
Issue or Number:1
PubMed Central ID:PMC3057625
Record Number:CaltechAUTHORS:20110224-100557609
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20110224-100557609
Official Citation:Lavallo, V., El-Batta, A., Bertrand, G. and Grubbs, R. H. (2011), Insights Into the Carbene-Initiated Aggregation of [Fe(cot)2]. Angewandte Chemie International Edition, 50: 268–271. doi: 10.1002/anie.201005212
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:22471
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:25 Feb 2011 21:30
Last Modified:03 Oct 2019 02:38

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