CaltechAUTHORS
  A Caltech Library Service

Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

Moret, Marc-Etienne and Peters, Jonas C. (2011) Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand. Angewandte Chemie International Edition, 50 (9). pp. 2063-2067. ISSN 1433-7851. PMCID PMC4165522. https://resolver.caltech.edu/CaltechAUTHORS:20110329-153028868

[img] PDF - Accepted Version
See Usage Policy.

1056Kb

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20110329-153028868

Abstract

Adaptable metallaboratranes: A tris- (phosphino)borane ligand stabilizes both low-valent Fe-N_2 complexes and a mid-valent imido species with a Fe≡NAr bond, thanks to its ability to shuttle between trigonal-bipyramidal and pseudotetrahedral geometries by elongation of the apical iron–boron bond (see picture)


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/anie.201006918DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/anie.201006918/abstractPublisherArticle
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4165522PubMed CentralArticle
ORCID:
AuthorORCID
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: November 4, 2010. Article first published online: 26 January 2011. This work was supported by the NIH (GM 070757). M.-E.M. acknowledges a Fellowship for Prospective Researchers from the Swiss National Science Foundation. We thank Charlene Tsay and Larry Henling for crystallographic assistance, as well as David VanderVelde for assistance with DOSY experiments and Angelo Di Bilio for EPR measurements.
Funders:
Funding AgencyGrant Number
NIHGM 070757
Swiss National Science FoundationUNSPECIFIED
Subject Keywords:iron; metallaboratranes; multiple bonds; nitrogen fixation; phosphinoborane ligands
Issue or Number:9
PubMed Central ID:PMC4165522
Record Number:CaltechAUTHORS:20110329-153028868
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20110329-153028868
Official Citation:Moret, M.-E. and Peters, J. C. (2011), Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand. Angewandte Chemie International Edition, 50: 2063–2067. doi: 10.1002/anie.201006918
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:23163
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:01 Apr 2011 20:10
Last Modified:26 Nov 2019 11:15

Repository Staff Only: item control page