Moret, Marc-Etienne and Peters, Jonas C. (2011) Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand. Angewandte Chemie International Edition, 50 (9). pp. 2063-2067. ISSN 1433-7851. PMCID PMC4165522. https://resolver.caltech.edu/CaltechAUTHORS:20110329-153028868
![[img]](https://authors.library.caltech.edu/style/images/fileicons/application_pdf.png) |
PDF
- Accepted Version
See Usage Policy. 1056Kb |
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20110329-153028868
Abstract
Adaptable metallaboratranes: A tris- (phosphino)borane ligand stabilizes both low-valent Fe-N_2 complexes and a mid-valent imido species with a Fe≡NAr bond, thanks to its ability to shuttle between trigonal-bipyramidal and pseudotetrahedral geometries by elongation of the apical iron–boron bond (see picture)
| Item Type: | Article | ||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| ||||||||||||
| ORCID: |
| ||||||||||||
| Additional Information: | © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: November 4, 2010. Article first published online: 26 January 2011. This work was supported by the NIH (GM 070757). M.-E.M. acknowledges a Fellowship for Prospective Researchers from the Swiss National Science Foundation. We thank Charlene Tsay and Larry Henling for crystallographic assistance, as well as David VanderVelde for assistance with DOSY experiments and Angelo Di Bilio for EPR measurements. | ||||||||||||
| Funders: |
| ||||||||||||
| Subject Keywords: | iron; metallaboratranes; multiple bonds; nitrogen fixation; phosphinoborane ligands | ||||||||||||
| Issue or Number: | 9 | ||||||||||||
| PubMed Central ID: | PMC4165522 | ||||||||||||
| Record Number: | CaltechAUTHORS:20110329-153028868 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20110329-153028868 | ||||||||||||
| Official Citation: | Moret, M.-E. and Peters, J. C. (2011), Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand. Angewandte Chemie International Edition, 50: 2063–2067. doi: 10.1002/anie.201006918 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 23163 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Jason Perez | ||||||||||||
| Deposited On: | 01 Apr 2011 20:10 | ||||||||||||
| Last Modified: | 26 Nov 2019 11:15 |
Repository Staff Only: item control page
