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Atomic Force Microscopy Characterization of Room-Temperature Adlayers of Small Organic Molecules through Graphene Templating

Cao, Peigen and Xu, Ke and Varghese, Joseph O. and Heath, James R. (2011) Atomic Force Microscopy Characterization of Room-Temperature Adlayers of Small Organic Molecules through Graphene Templating. Journal of the American Chemical Society, 133 (8). pp. 2334-2337. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20110404-093933135

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Abstract

We report on the use of graphene templating to investigate the room-temperature structure and dynamics of weakly bound adlayers at the interfaces between solids and vapors of small organic molecules. Monolayer graphene sheets are employed to preserve and template molecularly thin adlayers of tetrahydrofuran (THF) and cyclohexane on atomically flat mica substrates, thus permitting a structural characterization of the adlayers under ambient conditions through atomic force microscopy. We found the first two adlayers of both molecules adsorb in a layer-by-layer fashion, and atomically flat two-dimensional islands are observed for both the first and the second adlayers. THF adlayers form initially as rounded islands but, over a period of weeks, evolve into faceted islands, suggesting that the adlayers possess both liquid and solid properties at room temperature. Cyclohexane adlayers form crystal-like faceted islands and are immobile under the graphene template. The heights of the second adlayers of THF and cyclohexane are measured to be 0.44 ± 0.02 and 0.50 ± 0.02 nm, respectively, in good agreement with the layer thicknesses in the monoclinic crystal structure of THF and the Phase I “plastic crystal” structure of cyclohexane. The first adlayers appear slightly thinner for both molecules, indicative of interactions of the molecules with the mica substrate.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja108554pDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja108554pPublisherArticle
ORCID:
AuthorORCID
Heath, James R.0000-0001-5356-4385
Additional Information:© 2011 American Chemical Society. Received: September 22, 2010. Article ASAP February 04, 2011. Published In Issue March 02, 2011. We thank Wan Li (Cornell) for helpful discussions. We also thank G. Rossman for assistance in using the Micro Raman spectrometer. This work was funded by the Department of Energy (DE-FG02-04ER46175). J.O.V. acknowledges support from a National Science Foundation graduate fellowship.
Group:Kavli Nanoscience Institute
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-FG02-04ER46175
NSF Graduate Research FellowshipUNSPECIFIED
Record Number:CaltechAUTHORS:20110404-093933135
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20110404-093933135
Official Citation:Atomic Force Microscopy Characterization of Room-Temperature Adlayers of Small Organic Molecules through Graphene Templating Peigen Cao, Ke Xu, Joseph O. Varghese, James R. Heath Journal of the American Chemical Society 2011 133 (8), 2334-2337
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:23218
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:24 Jun 2011 20:18
Last Modified:25 Apr 2017 04:52

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