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Trinuclear first row transition metal complexes of a hexapyridyl, trialkoxy 1,3,5-triarylbenzene ligand

Tsui, Emily Y. and Kanady, Jacob S. and Day, Michael W. and Agapie, Theodor (2011) Trinuclear first row transition metal complexes of a hexapyridyl, trialkoxy 1,3,5-triarylbenzene ligand. Chemical Communications, 47 (14). pp. 4189-4191. ISSN 1359-7345.

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Trinuclear complexes of Mn^(II), Fe^(II), Co^(II), Ni^(II), Cu^(II), and Zn^(II) were synthesized using a ligand architecture based upon a 1,3,5- triarylbenzene core decorated with six pyridines and three alkoxide moieties. Characterization via X-ray diffraction, NMR, and magnetism studies is discussed.

Item Type:Article
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URLURL TypeDescription
Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2011 The Royal Society of Chemistry. Received 16th December 2010, Accepted 14th February 2011. We thank Lawrence M. Henling for crystallographic assistance. We are grateful to Caltech, Chemistry Department Dow Fellowship (JSK), and NSF GRFP (EYT) for funding. The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to Caltech, CHE-0639094. SQUID data were collected at the MMRC of the Beckman Institute of the California Institute of Technology.
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Dow Chemical CompanyUNSPECIFIED
NSF Graduate Research FellowshipUNSPECIFIED
Issue or Number:14
Record Number:CaltechAUTHORS:20110420-090320294
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:23389
Deposited By: Tony Diaz
Deposited On:22 Apr 2011 17:05
Last Modified:03 Oct 2019 02:46

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