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An Unusual Hydrogen Migration/C−H Activation Reaction with Group 3 Metals

Williams, Bryan N. and Benitez, Diego and Miller, Kevin L. and Tkatchouk, Ekaterina and Goddard, William A., III and Diaconescu, Paula L. (2011) An Unusual Hydrogen Migration/C−H Activation Reaction with Group 3 Metals. Journal of the American Chemical Society, 133 (13). pp. 4680-4683. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20110504-140724328

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Abstract

A novel hydrogen migration from the phenyl ring to the pyridine ring of an yttrium pyridyl complex supported by a 1,1′-ferrocene diamide ligand is reported. Density functional theory calculations were instrumental in probing the mechanism for this transformation.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja110505rDOIUNSPECIFIED
http://pubs.acs.org/doi/abs/10.1021/ja110505rPublisherUNSPECIFIED
ORCID:
AuthorORCID
Goddard, William A., III0000-0003-0097-5716
Diaconescu, Paula L.0000-0003-2732-4155
Additional Information:© 2011 American Chemical Society. Received: November 22, 2010. Published: March 09, 2011. This work was supported by UCLA, the Sloan Foundation, and NSF (Grant CHE-0847735). Computational facilities were funded by grants from ARO-DURIP and ONR-DURIP. D.B., E.T., and W.A.G. acknowledge support from DOE (DE-PS36- 08GO98004P).
Funders:
Funding AgencyGrant Number
UCLAUNSPECIFIED
Sloan FoundationUNSPECIFIED
NSFCHE-0847735
Army Research Office (ARO)-Defense University Research Instrumentation Program (DURIP)UNSPECIFIED
Office of Naval Research (ONR)-Defense University Research Instrumentation Program (DURIP)UNSPECIFIED
Department of Energy (DOE)DE-PS36-08GO98004P
Issue or Number:13
Record Number:CaltechAUTHORS:20110504-140724328
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20110504-140724328
Official Citation:An Unusual Hydrogen Migration/C−H Activation Reaction with Group 3 Metals Bryan N. Williams, Diego Benitez, Kevin L. Miller, Ekaterina Tkatchouk, William A. Goddard III, Paula L. Diaconescu Journal of the American Chemical Society 2011 133 (13), 4680-4683
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:23555
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:11 May 2011 16:34
Last Modified:09 Mar 2020 13:18

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