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Dinitrogen Complexes of Sulfur-Ligated Iron

Takaoka, Ayumi and Mankad, Neal P. and Peters, Jonas C. (2011) Dinitrogen Complexes of Sulfur-Ligated Iron. Journal of the American Chemical Society, 133 (22). pp. 8440-8443. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20110628-093114193

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Abstract

We report a unique class of dinitrogen complexes of iron featuring sulfur donors in the ancillary ligand. The ligands utilized are related to the recently studied tris(phosphino)silyl ligands (2-R_2PC_6H_4)_3Si (R = Ph, iPr) but have one or two phosphine arms replaced with thioether donors. Depending on the number of phosphine arms replaced, both mononuclear and dinuclear iron complexes with dinitrogen are accessible. These complexes contribute to a desirable class of model complexes that possess both dinitrogen and sulfur ligands in the immediate iron coordination sphere.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja2020907 DOIUNSPECIFIED
http://pubs.acs.org/doi/abs/10.1021/ja2020907PublisherUNSPECIFIED
ORCID:
AuthorORCID
Peters, Jonas C. 0000-0002-6610-4414
Additional Information:© 2011 American Chemical Society. Received: March 7, 2011. Published: May 16, 2011. This work was supported by the NIH (GM070757). Charlene Tsay and Larry Henling are acknowledged for crystallographic assistance. Prof. George Rossman is acknowledged for use of his NIR spectrometer. Dr. Dave Harris is acknowledged for useful discussions of the magnetic data.
Funders:
Funding AgencyGrant Number
NIHGM070757
Issue or Number:22
Record Number:CaltechAUTHORS:20110628-093114193
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20110628-093114193
Official Citation:Dinitrogen Complexes of Sulfur-Ligated Iron Ayumi Takaoka, Neal P. Mankad, Jonas C. Peters Journal of the American Chemical Society 2011 133 (22), 8440-8443
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:24235
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:28 Jun 2011 23:12
Last Modified:26 Nov 2019 11:15

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