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Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d^(10) and s^2 Centers

Moret, Marc-Etienne (2011) Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d^(10) and s^2 Centers. In: Higher Oxidation State Organopalladium and Platinum Chemistry. Topics in Organometallic Chemistry. No.35. Springer Verlag , New York, pp. 157-184. ISBN 978-3-642-17428-5. https://resolver.caltech.edu/CaltechAUTHORS:20110901-082942372

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Abstract

Square-planar palladium(II) and platinum(II) complexes with a high-lying filled d_(z²) orbital can act as metalloligands for Lewis-acidic metal centers such as d^(10) and s^2 cations. This behavior is promoted by hard ligands such as σ-bound hydrocarbyl ligands. A wide diversity of structural motifs based on this kind of donor–acceptor metal–metal bonds has been discovered in the last decades. This chapter reviews the coordination chemistry of metalloligands derived from alkyl, aryl, alkynyl, and carbene complexes of palladium(II) and platinum(II). The specific reactivity of the resulting bimetallic complexes is also addressed.


Item Type:Book Section
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1007/978-3-642-17429-2_7 DOIUNSPECIFIED
http://www.springerlink.com/content/034176q4g5535920/PublisherUNSPECIFIED
Additional Information:© 2011 Springer Verlag. I am indebted to Prof. Dr. Peter Chen for his generous support and many stimulating discussions during the elaboration of this chapter. Financial support from the Swiss National Foundation is acknowledged.
Funders:
Funding AgencyGrant Number
Swiss National Foundation (SNF)UNSPECIFIED
Subject Keywords:Heterobimetallic Complexes; Metal–metal bonds; Palladium; Platinum; Transmetalation
Series Name:Topics in Organometallic Chemistry
Issue or Number:35
Record Number:CaltechAUTHORS:20110901-082942372
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20110901-082942372
Official Citation:Moret, Marc-Etienne (2011) ChemInform Abstract: Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis Acidic d10 and s2 Centers. ChemInform 42(35)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:25192
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:01 Sep 2011 20:03
Last Modified:03 Oct 2019 03:03

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