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Iridium complexes bearing a PNP ligand, favoring facile C(sp^3)–H bond cleavage

Lokare, Kapil S. and Nielsen, Robert J. and Yousufuddin, Muhammed and Goddard, William A., III and Periana, Roy A. (2011) Iridium complexes bearing a PNP ligand, favoring facile C(sp^3)–H bond cleavage. Dalton Transactions, 40 (36). pp. 9094-9097. ISSN 1477-9226.

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Hydrogen iodide is lost upon reaction of PNP with IrI_3, where PNP = 2,6-bis-(di-t-butylphosphinomethyl)pyridine to give crystallographically characterized Ir(PNP)*(I)_2, which reacts with H_2 to give Ir(PNP)(H)(I)_2. Ir(PNP)(Cl)_3 is relatively inert towards the intramolecular C–H activation of the tert-butyl's of the PNP ligand.

Item Type:Article
Related URLs:
URLURL TypeDescription
Nielsen, Robert J.0000-0002-7962-0186
Goddard, William A., III0000-0003-0097-5716
Periana, Roy A.0000-0001-7838-257X
Additional Information:© 2011 The Royal Society of Chemistry. Received 4th April 2011. Accepted 6th July 2011. First published on the web 10th August 2011. This material is based upon work supported by Chevron Energy Technology Company, by the Center for Catalytic Hydrocarbon Functionalization, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DOE DE-SC000-1298 and by Scripps Florida.
Funding AgencyGrant Number
Chevron Energy Technology CompanyUNSPECIFIED
Department of Energy (DOE)DE-SC000-1298
Scripps FloridaUNSPECIFIED
Issue or Number:36
Record Number:CaltechAUTHORS:20110922-155211533
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Official Citation:Iridium complexes bearing a PNP ligand, favoring facile C(sp3)–H bond cleavage Kapil S. Lokare, Robert J. Nielsen, Muhammed Yousufuddin, William A. Goddard III and Roy A. Periana Dalton Trans., 2011, 40, 9094-9097 DOI: 10.1039/C1DT10577A
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:25415
Deposited By: Ruth Sustaita
Deposited On:23 Sep 2011 15:18
Last Modified:03 Oct 2019 03:05

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