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Short, Enantioselective Total Syntheses of (—)-8-Demethoxyrunanine and (—)-Cepharatines A, C, and D

Chuang, Kangway V. and Navarro, Raul and Reisman, Sarah E. (2011) Short, Enantioselective Total Syntheses of (—)-8-Demethoxyrunanine and (—)-Cepharatines A, C, and D. Angewandte Chemie International Edition, 50 (40). pp. 9447-9451. ISSN 1433-7851. PMCID PMC3520487. doi:10.1002/anie.201104487. https://resolver.caltech.edu/CaltechAUTHORS:20111005-093543509

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Abstract

All together! A unified synthetic strategy has resulted in the first enantioselective total syntheses of the natural products 8-demethoxyrunanine and cepharatines A, C, and D.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/anie.201104487DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/anie.201104487/abstractPublisherArticle
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3520487/PubMed CentralArticle
ORCID:
AuthorORCID
Chuang, Kangway V.0000-0002-0652-8071
Reisman, Sarah E.0000-0001-8244-9300
Additional Information:© 2011 Wiley-VCH Verlag GmbH & Co. Issue published online: 21 Sep 2011. Article first published online: 30 Aug 2011. Manuscript Received: 29 Jun 2011. We thank Dr. Michael Day and Mr. Larry Henling for X-ray crystallographic structural determination, as well as Prof. Brian Stoltz, Dr. Scott Virgil, and the Caltech Center for Catalysis and Chemical Synthesis for access to analytical equipment. Fellowship support was provided by the Gates Millennium Scholars Program (R.N.), the NIH (R.N., 1F31GM098025A) and the Amgen Scholars Program (K.V.C.). HRMS and X-ray crystallographic data were obtained on instruments purchased through awards to the California Institute of Technology by the NSF CRIF program (CHE-0639094, CHE-0541745). Financial support from the California Institute of Technology and the NSF (CAREER-1057143) is gratefully acknowledged.
Funders:
Funding AgencyGrant Number
Bill and Melinda Gates FoundationUNSPECIFIED
NIH Postdoctoral Fellowship1F31GM098025A
AmGenUNSPECIFIED
NSFCHE-0639094
NSFCHE-0541745
CaltechUNSPECIFIED
NSFCHE-1057143
Subject Keywords:alkaloids; asymmetric synthesis; cepharatines; hasubanan; total synthesis
Issue or Number:40
PubMed Central ID:PMC3520487
DOI:10.1002/anie.201104487
Record Number:CaltechAUTHORS:20111005-093543509
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20111005-093543509
Official Citation:Chuang, K. V., Navarro, R. and Reisman, S. E. (2011), Short, Enantioselective Total Syntheses of (−)-8-Demethoxyrunanine and (−)-Cepharatines A, C, and D. Angewandte Chemie International Edition, 50: 9447–9451. doi: 10.1002/anie.201104487
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:26589
Collection:CaltechAUTHORS
Deposited By:INVALID USER
Deposited On:05 Oct 2011 17:14
Last Modified:09 Nov 2021 16:42

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