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Terminal ruthenium carbido complexes as σ-donor ligands

Hejl, Andrew and Trnka, Tina M. and Day, Michael W. and Grubbs, Robert H. (2002) Terminal ruthenium carbido complexes as σ-donor ligands. Chemical Communications, 2002 (21). pp. 2524-2525. ISSN 1359-7345.

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The terminal carbido ligand of (Pcy_3)_2(Cl)_2RuC coordinates to other metal centers in a σ-donor fashion, as in (Pcy_3)_2(Cl)_2Ru≡C–Pd(Cl)_2(Sme_2) and (Pcy_3)_2(Cl)_2Ru≡C–Mo(CO)_5.

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Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2002 The Royal Society of Chemistry. Received 13 Aug 2002, Accepted 06 Sep 2002. First published on the web 30 Sep 2002. This research was supported by the US National Science Foundation. We thank Lawrence M. Henling for contributions to the crystallography, Jeremy May for chemicals, and Prof. Jonas Peters and Andrew Waltman for helpful discussions.
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Issue or Number:21
Record Number:CaltechAUTHORS:20111026-101215684
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:27437
Deposited By: Tony Diaz
Deposited On:26 Oct 2011 17:47
Last Modified:03 Oct 2019 03:23

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