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High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole

Bendix, Jesper and Gray, Harry B. and Golubkov, Galina and Gross, Zeev (2000) High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole. Chemical Communications, 2000 (19). pp. 1957-1958. ISSN 1359-7345. https://resolver.caltech.edu/CaltechAUTHORS:20111123-083709397

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Abstract

The X-ray structure, magnetic susceptibility, and high-field (high-frequency) EPR spectrum of manganese 5,10,15-tris(pentafluorophenyl) corrole unambiguously establish that the complex contains an isolated, slightly rhombic, manganese(III) center.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/b006299pDOIUNSPECIFIED
http://pubs.rsc.org/en/content/articlelanding/2000/cc/b006299pPublisherUNSPECIFIED
ORCID:
AuthorORCID
Gray, Harry B.0000-0002-7937-7876
Additional Information:© 2000 The Royal Society of Chemistry. Received 02 Aug 2000, Accepted 30 Aug 2000. First published on the web 21 Sep 2000. We thank Dr M. W. Day (Beckman Institute) for assistance with the crystal structure determination and Ms S. Mossin (University of Copenhagen) and Dr A.-L. Barra (CNRS, Grenoble) for recording the HF-EPR spectra. This research was supported by the Fund for the Promotion of Research at the Technion (Z. G.), the National Science Foundation (H. B. G.), and grant # 9800549 from the Danish Natural Science Research Council (J. B.).
Funders:
Funding AgencyGrant Number
Promotion of Research at the TechnionUNSPECIFIED
NSFUNSPECIFIED
Danish Natural Science Research Council9800549
Issue or Number:19
Record Number:CaltechAUTHORS:20111123-083709397
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20111123-083709397
Official Citation:High-field (high-frequency) EPR spectroscopy and structural characterization of a novel manganese(III) corrole Jesper Bendix, Harry B. Gray, Galina Golubkov and Zeev Gross Chem. Commun., 2000, 1957-1958 DOI: 10.1039/B006299P
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:27937
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:23 Nov 2011 17:27
Last Modified:22 Nov 2019 09:58

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