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Threshold zero‐kinetic‐energy photoelectron spectroscopy of the a^(3)Σ^+ state of NO^+

Wang, Kwanghsi and McKoy, V. (1996) Threshold zero‐kinetic‐energy photoelectron spectroscopy of the a^(3)Σ^+ state of NO^+. Journal of Chemical Physics, 104 (10). pp. 3433-3437. ISSN 0021-9606. doi:10.1063/1.471050.

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Results of calculations of the photoelectron spectra for single‐photon pulsed‐field ionization of the 1π orbital of the X (^2)Π (v″=0) ground state NO leading to the a ^(3)Σ^+ (v^(+)=0–2) excited ionic state are reported. Agreement between these calculated and recently measured spectra is very encouraging. Comparison of these spectra for ionization of the 1π level of NO (X  ^(2)Π) with those for the 2π orbital reveal significantly different spectral profiles and underlying dynamics for these two cases

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Additional Information:© 1996 American Institute of Physics. Received 6 September 1995; accepted 1 December 1995. This work was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the U.S. Department of Energy. We also acknowledge use of resources of the Jet Propulsion Laboratory/California Institute of Technology Y-MP2E/232 Supercomputer.
Funding AgencyGrant Number
Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Department of Energy (DOE)UNSPECIFIED
Subject Keywords:Cross sections; ionization; nitrogen oxides; photoelectron spectroscopy; rotational states; rydberg states; threshold energy; ultraviolet radiation
Issue or Number:10
Classification Code:PACS: 33.60.+q; 33.80.Rv
Record Number:CaltechAUTHORS:20120208-162722792
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:29218
Deposited On:09 Feb 2012 18:16
Last Modified:09 Nov 2021 17:05

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