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H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex

Iluc, Vlad M. and Fedorov, Alexey and Grubbs, Robert H. (2011) H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex. Organometallics, 31 (1). pp. 39-41. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20120210-151229549

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Abstract

A PNP-pincer iridium dihydride performs the H/D exchange between aromatic substrates and tertiary hydrosilanes and D_(2)O or C_(6)D_(6). Complete incorporation of deuterium into sterically accessible C_(ar)–H and Si–H bonds was observed at a moderate temperature of 80 °C.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/om201049pDOIArticle
http://pubs.acs.org/doi/abs/10.1021/om201049pPublisherArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2011 American Chemical Society. Received: October 28, 2011; Published: December 15, 2011. Generous financial support of this research was provided by BP (MC2 initiative). A.F. thanks the Swiss National Science Foundation for a postdoctoral fellowship.
Funders:
Funding AgencyGrant Number
BP MC2 IntiativeUNSPECIFIED
Swiss National Science Foundation (SNSF)UNSPECIFIED
Issue or Number:1
Record Number:CaltechAUTHORS:20120210-151229549
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20120210-151229549
Official Citation:H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex Vlad M. Iluc, Alexey Fedorov, and Robert H. Grubbs Organometallics 2012 31 (1), 39-41
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:29247
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:10 Feb 2012 23:56
Last Modified:03 Oct 2019 03:39

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