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High-Resolution Photoelectron Spectroscopy of Molecules

Wang, Kwanghsi and McKoy, Vincent (1995) High-Resolution Photoelectron Spectroscopy of Molecules. Annual Review of Physical Chemistry, 46 . pp. 275-304. ISSN 0066-426X. doi:10.1146/annurev.pc.46.100195.001423.

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Rotationally resolved photoelectron spectra can provide significant insight into the underlying dynamics of molecular photoionization. Here, we discuss and compare results of recent theoretical studies of rotationally resolved photoelectron spectra with measurements for molecules such as HBr, OH, NO, N_2, CO, H_2O, H_2CO, and CH_3. These studies reveal the rich dynamics of quantum-state-specific studies of molecular photoionization and provide a robust description of key spectral features resulting from Cooper minima, autoionization, alignment, partial-wave mixing, and interference in related experimental studies.

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Additional Information:© 1995 Annual reviews, Inc. This work was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the US Department of Energy. We also acknowledge use of the resources of the Jet Propulsion Laboratory/California Institute of Technology CRAY Y-MP2E/116 Supercomputer.
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Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Department of Energy (DOE)UNSPECIFIED
Subject Keywords:REMPI, ZEKE, Cooper minima, parity selection rules, photoelectron matrix elements
Record Number:CaltechAUTHORS:20120215-110943863
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:29305
Deposited By: Tony Diaz
Deposited On:20 Mar 2012 23:00
Last Modified:09 Nov 2021 17:05

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