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The Electronic Transition Moment Function of the E^1Π_u–X^1Σ_g^+ System of Ag_2^(*1)

Antić-Jovanović, A. and Kuzmanović, M. and Khakoo, M. A. and Laher, R. R. (2011) The Electronic Transition Moment Function of the E^1Π_u–X^1Σ_g^+ System of Ag_2^(*1). Russian Journal of Physical Chemistry A, 85 (13). pp. 2363-2367. ISSN 0036-0244.

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Measurement of relative band strengths of 10 absorption bands of the E^1Π_u-X^1Σ_g^+ system of diatomic silver, ^(107,109)Ag_2, was performed for the first time. Theoretical analysis of the experimental data, based on Rydberg-Klein-Rees potential energy curves, revealed that assumption of the r-centroid approximation is valid for this system. Comparison of the measured and computed band strength ratios for 5 pairs of bands having common lower levels led to the following linear relative electronic transition moment function for the ^(107,109)Ag_2 E-X band system: R_e(r_(V'V"))=236r_(V'V")−564, in arbitrary units, over the 2.65–2.73 Å of internuclear distance.

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Additional Information:© 2011 Pleiades Publishing, Ltd. Received December 22, 2010. The article is published in the original. This work was supported by the Ministry of Sciences of the Republic of Serbia, project no. 142065 and in part by the U.S. National Aeronautics and Space Administration (NASA).
Funding AgencyGrant Number
Ministry of Science of the Republic of Serbia142065
Subject Keywords:electronic transition; absorption bands; E^1Π_u-X^1Σ_g^+ system of Ag_2
Issue or Number:13
Record Number:CaltechAUTHORS:20120222-090143515
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Official Citation:The electronic transition moment function of the E1Πu-X1Σ g+ system of Ag2, pp 2363-2367 A. Antić-Jovanović, M. Kuzmanović, M. A. Khakoo and R. R. Laher
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:29406
Deposited By: Ruth Sustaita
Deposited On:22 Feb 2012 17:40
Last Modified:03 Oct 2019 03:41

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