Marder, Seth R. and Cheng, Lap-Tak and Tiemann, Bruce G. (1992) The First Molecular Electronic Hyperpolarizabilities of Highly Polarizable Organic Molecules: 2,6-Di-tert-butylindoanilines. Journal of the Chemical Society. Chemical Communications (9). pp. 672-674. ISSN 0022-4936. doi:10.1039/c39920000672. https://resolver.caltech.edu/CaltechAUTHORS:20120330-072052875
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Abstract
The first molecular hyperpolarizabilities (β) of a series of 2,6-di-tert-butylindoanilines, measured by electric-field-induced second harmonic generation are somewhat more sensitive to donor strength than was found for analogously substituted nitrostilbenes, and dimethylindoaniline has a β roughly twice that of its 2,6 di-tert-butylated analogue, measured in chloroform; solvatochromic measurements on the former compound suggest that this decrease in hyperpolarizability is consistent with a bound-solvent effect.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1992 Royal Society of Chemistry. Received, 3rd December 1991; Com. I/06124K. Research through agreements with the National Aeronautics and Space Administration (NASA). | |||||||||
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| Issue or Number: | 9 | |||||||||
| DOI: | 10.1039/c39920000672 | |||||||||
| Record Number: | CaltechAUTHORS:20120330-072052875 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20120330-072052875 | |||||||||
| Official Citation: | The first molecular electronic hyperpolarizabilities of highly polarizable organic molecules: 2,6-di-tert-butylindoanilines Seth R. Marder, Lap-Tak Cheng and Bruce G. Tiemann J. Chem. Soc., Chem. Commun., 1992, 672-674 DOI: 10.1039/C39920000672 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 29905 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 30 Mar 2012 14:56 | |||||||||
| Last Modified: | 09 Nov 2021 19:32 |
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