Rotationally resolved photoelectron angular distributions in resonance enhanced multiphoton ionization of NO

Rudolph, H. and McKoy, V. (1989) Rotationally resolved photoelectron angular distributions in resonance enhanced multiphoton ionization of NO. Journal of Chemical Physics, 91 (4). pp. 2235-2238. ISSN 0021-9606. doi:10.1063/1.457031. https://resolver.caltech.edu/CaltechAUTHORS:20120530-144040127

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Abstract

We report calculated ionic rotational branching ratios and associated photoelectron angular distributions for (1+1′) resonance enhanced multiphoton ionization (REMPI) via the R_(21)(20.5), P_(21)+Q_(11)(25.5), and P_(11)(22.5) branches of the A ^2 Σ^+(3sσ) state of NO. The branching ratios are dominated by even angular momentum transfer peaks, in agreement with the ΔN+l=odd (ΔN≡N+−Ni ) selection rule. Whereas the calculated photoelectron angular distributions are very branch dependent alignment, the ionic branching ratios are found to be less so. The present calculated results agree well with the experimental results of Allendorf et al.

Item Type:

Article

Related URLs:

URL	URL Type	Description
http://dx.doi.org/10.1063/1.457031	DOI	UNSPECIFIED
http://jcp.aip.org/resource/1/jcpsa6/v91/i4/p2235_s1	Publisher	UNSPECIFIED

Additional Information:

© 1989 American Institute of Physics. Received 18 April 1989; accepted 5 May 1989. This material is based on research supported by the National Science Foundation under Grant No. CHE-8521391, by AFOSR under Grant. No. 87-0039 and by the Office of Health and Environmental Research of DOE (DE-FG03- 87ER60513). The authors also acknowledge use of the resources of the San Diego Supercomputer which is supported by the National Science Foundation. H.R. gratefully acknowledges support from the NATO Science Fellowship Programme.

Funders:

Funding Agency	Grant Number
NSF	CHE-8521391
Air Force Office of Scientific Research (AFOSR)	87-0039
Department of Energy (DOE) Office of Health and Environmental Research	DE-FG03-87ER60513
NATO Science Fellowship Programme	UNSPECIFIED
NSF	UNSPECIFIED

Subject Keywords:

ROTATIONAL STATES, PHOTOELECTRON SPECTROSCOPY, ANGULAR DISTRIBUTION, RESONANCE, MULTI−PHOTON PROCESSES, PHOTOIONIZATION, NITRIC OXIDE

Issue or Number:

Classification Code:

PACS: 33.60.+q; 33.80.Rv

DOI:

10.1063/1.457031

Record Number:

CaltechAUTHORS:20120530-144040127

Persistent URL:

https://resolver.caltech.edu/CaltechAUTHORS:20120530-144040127

Official Citation:

Rotationally resolved photoelectron angular distributions in resonance enhanced multiphoton ionization of NO H. Rudolph and V. McKoy J. Chem. Phys. 91, 2235 (1989); http://dx.doi.org/10.1063/1.457031

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ID Code:

31724

Collection:

CaltechAUTHORS

Deposited By:

Ruth Sustaita

Deposited On:

30 May 2012 22:05

Last Modified:

09 Nov 2021 19:59

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