Pauling, Linus and Sherman, J. (1933) The Nature of the Chemical Bond. VII. The Calculation of Resonance Energy in Conjugated Systems. Journal of Chemical Physics, 1 (10). pp. 679-686. ISSN 0021-9606. doi:10.1063/1.1749226. https://resolver.caltech.edu/CaltechAUTHORS:20120801-164037906
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Abstract
The quantum‐mechanical treatment previously applied to benzene, naphthalene, and the hydrocarbon free radicals is used in the calculation of extra resonance energy of conjugation in systems of double bonds, the dihydronaphthalenes and dihydroanthracenes, phenylethylene, stilbene, isostilbene, triphenylethylene, tetraphenylethylene, biphenyl, o, m, and p‐diphenylbenzene, and 1,3,5‐triphenylbenzene. The calculated values, which are in approximate agreement with empirical values from thermochemical data, are used in the discussion of chemical properties and in the formulation of rules regarding conjugation in overlapping systems.
| Item Type: | Article | ||||||
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| Additional Information: | © 1933 American Institute of Physics. Received 3 July 1933. Contribution No. 370. We are indebted to Professor G. E. K. Branch and to Dr. G. W. Wheland for pointing this out to us. | ||||||
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| Issue or Number: | 10 | ||||||
| DOI: | 10.1063/1.1749226 | ||||||
| Record Number: | CaltechAUTHORS:20120801-164037906 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20120801-164037906 | ||||||
| Official Citation: | The Nature of the Chemical Bond. VII. The Calculation of Resonance Energy in Conjugated Systems Linus Pauling and J. Sherman, J. Chem. Phys. 1, 679 (1933), DOI:10.1063/1.1749226 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 32852 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | INVALID USER | ||||||
| Deposited On: | 02 Aug 2012 14:38 | ||||||
| Last Modified: | 09 Nov 2021 21:30 |
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