Grubbs, Robert H. and Miyashita, Akira (1977) The Metallacyclopentane-Olefin Interchange Reaction. Journal of the Chemical Society. Chemical Communications, 1977 (23). pp. 864-865. ISSN 0022-4936. doi:10.1039/C39770000864. https://resolver.caltech.edu/CaltechAUTHORS:20120808-071724607
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Abstract
Tris(triphenylphosphine)tetramethylenenickel(II) and biscyclopentadienyltetramethylenetitanium, prepared from the reaction of a 1,4-dilithiobutane and the transition metal dihalides react with olefins to produce substituted metallacyclopentanes; the stereochemistry and substitution pattern of the metallocycles formed from propene, octa-1,7-diene, and norbornadiene has been determined.
Item Type: | Article | |||||||||
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Additional Information: | © 1977 Royal Society of Chemistry. Received, 8th August 1977; Com. 829. The authors thank the National Science Foundation for support of this work. | |||||||||
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Issue or Number: | 23 | |||||||||
DOI: | 10.1039/C39770000864 | |||||||||
Record Number: | CaltechAUTHORS:20120808-071724607 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20120808-071724607 | |||||||||
Official Citation: | The metallacyclopentane–olefin interchange reaction Robert H. Grubbs and Akira Miyashita J. Chem. Soc., Chem. Commun., 1977, 864-865 DOI: 10.1039/C39770000864 | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 32999 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Ruth Sustaita | |||||||||
Deposited On: | 08 Aug 2012 14:34 | |||||||||
Last Modified: | 09 Nov 2021 21:31 |
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