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The Metallacyclopentane-Olefin Interchange Reaction

Grubbs, Robert H. and Miyashita, Akira (1977) The Metallacyclopentane-Olefin Interchange Reaction. Journal of the Chemical Society. Chemical Communications, 1977 (23). pp. 864-865. ISSN 0022-4936. doi:10.1039/C39770000864.

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Tris(triphenylphosphine)tetramethylenenickel(II) and biscyclopentadienyltetramethylenetitanium, prepared from the reaction of a 1,4-dilithiobutane and the transition metal dihalides react with olefins to produce substituted metallacyclopentanes; the stereochemistry and substitution pattern of the metallocycles formed from propene, octa-1,7-diene, and norbornadiene has been determined.

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Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 1977 Royal Society of Chemistry. Received, 8th August 1977; Com. 829. The authors thank the National Science Foundation for support of this work.
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Issue or Number:23
Record Number:CaltechAUTHORS:20120808-071724607
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Official Citation:The metallacyclopentane–olefin interchange reaction Robert H. Grubbs and Akira Miyashita J. Chem. Soc., Chem. Commun., 1977, 864-865 DOI: 10.1039/C39770000864
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:32999
Deposited By: Ruth Sustaita
Deposited On:08 Aug 2012 14:34
Last Modified:09 Nov 2021 21:31

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