Wrighton, Mark and Bredesen, Dale and Hammond, George S. and Gray, Harry B. (1972) Deactivation of biacetyl triplets by cyanocobaltate(III) complexes. Journal of the Chemical Society. Chemical Communications (18). pp. 1018-1019. ISSN 0022-4936. doi:10.1039/C39720001018. https://resolver.caltech.edu/CaltechAUTHORS:20120814-131933097
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Abstract
The rate of electronic energy transfer from biacetyl triplets to Co(CN)_(5)(X)^(n–)(X = CN^–, MeCN, pyridine, N_(3)^–, H_(2)O, or SCN^–) is strongly dependent on the energy of the first spin-allowed d–d transition of Co(CN)_(5)(X)^(n–), and (for X = CN^–, N_(3)^–, and SCN^–) the direct and sensitized photosubstitution yields are the same, implying a common reactive state.
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| Additional Information: | © 1972 Royal Society of Chemistry. Received: 12 June 1972; Com. 999. This research was supported by the Directorate of Chemical Sciences, Air Force Office of Scientific Research, and the Army Research Office, Durham. | |||||||||
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| Issue or Number: | 18 | |||||||||
| DOI: | 10.1039/C39720001018 | |||||||||
| Record Number: | CaltechAUTHORS:20120814-131933097 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20120814-131933097 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 33178 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | INVALID USER | |||||||||
| Deposited On: | 14 Aug 2012 23:17 | |||||||||
| Last Modified: | 09 Nov 2021 21:33 |
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