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New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I)

Bercaw, John and Guastalla, Giovanni and Halpern, Jack (1971) New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I). Journal of the Chemical Society D: Chemical Communications, 1971 (24). pp. 1594-1595. ISSN 0577-6171. doi:10.1039/C29710001594.

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The preparation and characterization of several series of mixed ligand cobalt(I) complexes of the types [Co(CN)_2(CO)_2(PR_3)]–, [Co(CN)_2(CO)(PR_3)_2]–, and [Co(CN)(CO)_2(PR_3)_2], prepared by the reactions of tertiary phosphines (PR_3) with [Co(CN)_3(CO)_2]^(2–), are described and some novel aspects of their chemistry are discussed.

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Additional Information:© 1971 Royal Society of Chemistry. Received, September 20th, 1971; Com. 1650. Support of this work by the National Science Foundation and the National Institutes of Health is gratefully acknowledged.
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Issue or Number:24
Record Number:CaltechAUTHORS:20120815-073948090
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Official Citation:New cobalt(I) complexes derived from dicarbonyltricyanocobaltate(I) John Bercaw, Giovanni Guastalla and Jack Halpern, J. Chem. Soc. D, 1971, 1594 DOI: 10.1039/C29710001594
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:33193
Deposited By: Ruth Sustaita
Deposited On:15 Aug 2012 15:03
Last Modified:09 Nov 2021 21:33

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