Gray, Harry B. and Ballhausen, C. J. (1962) On the Optical Spectra of Some Transition Metal Pentacyanonitrosyl Complexes. Journal of Chemical Physics, 36 (5). pp. 1151-1153. ISSN 0021-9606. doi:10.1063/1.1732707. https://resolver.caltech.edu/CaltechAUTHORS:20120816-110715372
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Abstract
The visible absorption spectra of the ions [Fe(CN)_(5)NO]^(2-), [Mn(CN)_(5)NO]^(3—), and [Cr(CN)_(5)NO]^(3—) are interpreted using a crystal field level scheme of C_(4v) symmetry. Assuming a strong axial compression to be present a self‐consistent assignment is obtained for both the 3d^5 and 3d^6 electronic configurations.
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| Additional Information: | © 1962 American Institute of Physics. Received 24 August 1961. National Science Foundation Postdoctoral Fellow, 1960-61. | |||||||||
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| Issue or Number: | 5 | |||||||||
| DOI: | 10.1063/1.1732707 | |||||||||
| Record Number: | CaltechAUTHORS:20120816-110715372 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20120816-110715372 | |||||||||
| Official Citation: | On the Optical Spectra of Some Transition Metal Pentacyanonitrosyl Complexes Harry B. Gray and C. J. Ballhausen, J. Chem. Phys. 36, 1151 (1962), DOI:10.1063/1.1732707 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 33262 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | INVALID USER | |||||||||
| Deposited On: | 16 Aug 2012 18:53 | |||||||||
| Last Modified: | 09 Nov 2021 21:33 |
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