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Measurement of the carbon content of silicate glasses using the ^(12)C(d,p_0)^(13)C nuclear reaction

Fine, G. J. and Stolper, E. M. and Mendenhall, M. H. and Livi, R. P. and Tombrello, T. A. (1985) Measurement of the carbon content of silicate glasses using the ^(12)C(d,p_0)^(13)C nuclear reaction. In: Microbeam analysis. San Francisco Press , San Francisco, CA, pp. 241-245.

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Carbon dioxide is a significant dissolved component in a wide range of magmas and ubiquitous in gasses associated with volcanism. This fact has motivated extensive study of the influence of CO_2 on the petrogenesis of many magma types. Despite its importance, the absolute concentrations of dissolved C in silicate glasses quenched from these magmas are not well known. Standard carbon analysis techniques (e. g., gas manometry, quadruple mass spectrometry, gas chromatography) have been applied to natural and synthetic C-bearing glasses, but a comparison of the results of these techniques shows wide discrepancies. These bulk analytic techniques are destructive and require relatively large samples; in addition, the effects of crystals, alteration phases, and C in bubbles (versus C dissolved in the glass) are often difficult to evaluate.

Item Type:Book Section
Stolper, E. M.0000-0001-8008-8804
Additional Information:© 1985 San Francisco Press, Inc.
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Caltech Division of Geological and Planetary Sciences4200
Record Number:CaltechAUTHORS:20120822-085210462
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:33436
Deposited By: Tony Diaz
Deposited On:28 Aug 2012 21:05
Last Modified:03 Oct 2019 04:09

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