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Volatilization kinetics of silicon carbide in reducing gases: An experimental study with applications to the survival of presolar grains in the solar nebula

Mendybaev, R. A. and Beckett, J. R. and Grossman, L. and Stolper, E. and Cooper, R. F. and Bradley, J. P. (2002) Volatilization kinetics of silicon carbide in reducing gases: An experimental study with applications to the survival of presolar grains in the solar nebula. Geochimica et Cosmochimica Acta, 66 (4). pp. 661-682. ISSN 0016-7037. https://resolver.caltech.edu/CaltechAUTHORS:20120823-114625514

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Abstract

The volatilization kinetics of single crystal α-SiC, polycrystalline β-SiC, and SiO_2 (cristobalite or glass) were determined in H_2-CO_2, CO-CO_2, and H_2-CO-CO_2 gas mixtures at oxygen fugacities between 1 log unit above and 10 log units below the iron-wüstite (IW) buffer and temperatures in the range 1151 to 1501°C. Detailed sets of experiments on SiC were conducted at 2.8 and 6.0 log units below IW (IW-2.8 and IW-6.0) at a variety of temperatures, and at 1300°C at a variety of oxygen fugacities. Transmission electron microscopic and Rutherford backscattering spectroscopic characterization of run products shows that the surface of SiC exposed to IW-2.8 is characterized by a thin (<1 μm thick), continuous layer of cristobalite. SiC exposed to IW-6.0 lacks such a layer (or its thickness is <0.01 μm), although some SiO_2 was found within pits and along incised grain boundaries. In H_2-CO_2 gas mixtures above ∼IW-3, the similarity of the SiC volatilization rate and of its dependence on temperature and fO_2 to that for SiO_2 suggests that SiC volatilization is controlled by volatilization of a SiO_2 layer that forms on the surface of the SiC. With decreasing log fO_2 from ∼IW-3 to ∼IW-6, the SiC volatilization rate is constant at constant temperature, whereas that for SiO_2 increases. The independence of the SiC volatilization rate from the gas composition under these conditions suggests that the rate-controlling step is a solid-solid reaction at the internal SiC/SiO_2 interface. For gas compositions more reducing than ∼IW-6, the SiC volatilization rate increases with decreasing fO_2, with both bare SiC surfaces and perhaps silica residing in pits and along incised grain boundaries contributing to the overall reaction rate. If the volatilization mechanism and reaction rate in the solar nebula were the same as in our H_2-CO_2 experiments at IW-6.0, then estimated lifetimes of 1-μm-diameter presolar SiC grains range from several thousand years at ∼900°C, to ∼1 yr at 1100°C, ∼1 d at 1300°C, and ∼1 h at 1400°C. The corresponding lifetimes for 10-μm SiC grains would be an order of magnitude longer. If the supply of oxidants to surfaces of presolar SiC grains were rate limiting—for example, at T > 1100°C for P^(tot)= 10^(−6) atm and sticking coefficient = 0.01, then the calculated lifetimes would be about 10 yr for 10-μm-diameter grains, essentially independent of temperature. The results thus imply that presolar SiC grains would survive short heating events associated with formation of chondrules (minutes) and calcium-, aluminum-rich inclusions (days), but would have been destroyed by exposure to hot (≥900°C) nebular gases in less than several thousand years unless they were coated with minerals inert to reaction with a nebular gas.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/S0016-7037(01)00802-XDOIArticle
http://www.sciencedirect.com/science/article/pii/S001670370100802XPublisherArticle
ORCID:
AuthorORCID
Stolper, E.0000-0001-8008-8804
Additional Information:© 2002 Elsevier Science Ltd. Received 26 April 2001; Revised 21 August 2001; Accepted 21 August 2001; Available online 8 February 2002. We are grateful to J. Goela, M. Pickering, and R. Taylor for providing us with CVD β-SiC; we thank P. Laurijsen and H. Kolker for single-crystal α-SiC. We thank Joe Pluth for his help with XRD and P. Cassen for insights into nebular dynamics. Avi Zangvil and Senol Pekin participated in useful discussions. Reviews by G. Huss, K. Lodders, N. Jacobson, and E. Opila greatly improved the manuscript. This work was supported by the National Aeronautics and Space Administration through grants NAGW-3212 (L.G.), NAG5-4476 (L.G.), NAG5-4318 (E.S.), and NAG5-6184 (E.S.). R.A.M.’s 680 R. A. Mendybaev et al. participation in the late stages of this study was made possible with funds from NASA grant NAG5-9378 to Frank M. Richter. Associate editor: U. Ott
Funders:
Funding AgencyGrant Number
NASANAGW-3212
NASANAG5-4476
NASANAG5-4318
NASANAG5-6184
NASANAG5-9378
Issue or Number:4
Record Number:CaltechAUTHORS:20120823-114625514
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20120823-114625514
Official Citation:R.A. Mendybaev, J.R. Beckett, L. Grossman, E. Stolper, R.F. Cooper, J.P. Bradley, Volatilization kinetics of silicon carbide in reducing gases: an experimental study with applications to the survival of presolar grains in the solar nebula, Geochimica et Cosmochimica Acta, Volume 66, Issue 4, 15 February 2002, Pages 661-682, ISSN 0016-7037, 10.1016/S0016-7037(01)00802-X. (http://www.sciencedirect.com/science/article/pii/S001670370100802X)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:33485
Collection:CaltechAUTHORS
Deposited By: Aucoeur Ngo
Deposited On:23 Aug 2012 20:18
Last Modified:03 Oct 2019 04:10

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