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A phase diagram for mid-ocean ridge basalts: Preliminary results and implications for petrogenesis

Stolper, Edward (1980) A phase diagram for mid-ocean ridge basalts: Preliminary results and implications for petrogenesis. Contributions to Mineralogy and Petrology, 74 (1). pp. 13-27. ISSN 0010-7999. doi:10.1007/BF00375485.

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Samples of a primitive mid-ocean ridge basalt (MORB) glass were encapsulated in a mixture of ol (Fo90) and opx (En90) and melted at 10, 15, and 20 kbar. After quenching, the basaltic glass was present as a pool within the ol + opx capsule, but its composition had changed so that it was saturated with ol and opx at the conditions of the experiment. By analyzing the quenched liquid, the location of the ol + opx cotectic in the complex, multicomponent system relevant to MORB genesis was determined. As pressure increases from 1 atm to 10 kbar the dry ol + opx cotectic moves from quartz tholeiitic to olivine tholeiitic compositions. With further increases in pressure, the cotectic continues to move toward the ol-di-plag join (i.e., toward alkalic compositions). Between 15 and 20 kbar, ol + opx + di-saturated liquids change from tholeiitic to alkalic in character although part of the ol + opx cotectic is still in the tholeiitic (i.e, hy-normative) part of composition space. At pressures of 10-15 kbar, tholeiitic liquids may be able to fractionate to alkalic liquids on the ol + di cotectic. Primitive MORB compositions come close to but do not actually lie on the ol + opx cotectic under any conditions studied. This suggests that not even the most primitive of known MORBs are primary melts of the mantle. The correspondence of most MORBs to the 1 atm ol + di + plag cotectic suggests that low pressure fractionation was involved in their genesis from parent liquids. Picritic liquids that have been proposed as parents to the MORB suite could equilibrate with harzburgite (or lherzolite) at 15~20 kbar and thus could be primary. Fractionation of ol from these liquids could yield primitive MORB liquids, but other primary liquids or more complex fractionation paths involving others phases in addition to ol cannot be ruled out. The possibility that these picritic liquids could equilibrate with ol+opx at 25-30 kbar cannot be ruled out.

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Stolper, Edward0000-0001-8008-8804
Additional Information:© 1980 Springer-Verlag. Received January 24. 1980; Accepted June 24, 1980. The experiments reported in this paper were conducted at Harvard University in the laboratory of Professor J.F. Hays and were supported by NSF grants EAR 79-06321, EAR 79-23977; NASA grant NGL 22-007-247; and the Committee on Experimental Geology and Geophysics of Harvard University. I thank W.B. Bryan, A.J. Irving, and D. Walker for making samples available to me and D. Eggler and D.C. Presnall for their reviews of the manuscript. Special thanks to D. Walker for preparing the projections of the MORB compositions from the catalog of Melson et al. (1977) that were used in Figs. 8 and 9. Contribution Number 3370, Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125.
Funding AgencyGrant Number
NSFEAR 79-06321
NSFEAR 79-23977
NASANGL 22-007-247
Harvard University Committee on Experimental Geology and GeophysicsUNSPECIFIED
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Caltech Division of Geological and Planetary Sciences3370
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ID Code:33491
Deposited On:24 Aug 2012 20:10
Last Modified:09 Nov 2021 21:35

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