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Dissociation and Isomerization of Vibrationally Excited Species. III

Marcus, R. A. (1965) Dissociation and Isomerization of Vibrationally Excited Species. III. Journal of Chemical Physics, 43 (8). pp. 2658-2661. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:20120827-131950075

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Abstract

The equations of Part I for the specific and over‐all unimolecular reaction‐rate constants are extended slightly by including centrifugal effects in a more detailed way and by making explicit allowance for possible reaction‐path degeneracy (optically or geometrically isomeric paths). The expression for reaction‐path degeneracy can be applied to other types of reactions in discussions of statistical factors in reaction rates.


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http://dx.doi.org/10.1063/1.1697191DOIUNSPECIFIED
http://link.aip.org/link/doi/10.1063/1.1697191PublisherUNSPECIFIED
Additional Information:© 1965 American Institute of Physics. Received 20 May 1965. Supported in part by a grant from the National Science Foundation. Presented in part at a symposium on reaction kinetics, American Physical Society, St. Louis, Missouri, March 1963 Supported in part by a grant from the National Science Foundation. Presented in part at a symposium on reaction kinetics, American Physical Society, St. Louis, Missouri, March 1963.
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Record Number:CaltechAUTHORS:20120827-131950075
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120827-131950075
Official Citation:Dissociation and Isomerization of Vibrationally Excited Species. III R. A. Marcus, J. Chem. Phys. 43, 2658 (1965), DOI:10.1063/1.1697191
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ID Code:33570
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Deposited By: Jason Perez
Deposited On:27 Aug 2012 21:20
Last Modified:26 Dec 2012 16:03

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