Marcus, R. A. (1963) Free Energy of Non equilibrium Polarization Systems. III. Statistical Mechanics of Homogeneous and Electrode Systems. Journal of Chemical Physics, 39 (7). pp. 1734-1740. ISSN 0021-9606. doi:10.1063/1.1734522. https://resolver.caltech.edu/CaltechAUTHORS:20120829-105437675
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Abstract
A statistical mechanical treatment is given for homogeneous and electrochemical systems having nonequilibrium dielectric polarization. A relation between the free energy of these systems and those of related equilibrium ones is deduced, having first been derived in Part II by a dielectric continuum treatment. The results can be applied to calculating polar contributions in the theory of electron transfers and in that of shifts of electronic spectra in condensed media. The effect of differences in polarizability (of a light emitting or absorbing molecule in its initial and final electronic states) on the polar term in the shift is included by a detailed statistical analysis, thereby extending Part II. Throughout, the "particle" description of the entities contributing to these phenomena is employed, so as to derive the results for rather general potential energy functions.
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| Additional Information: | © 1963 American Institute of Physics. Received 26 April 1963. Online Publication Date: 29 June 2004. Supported in part by the National Science Foundation. Alfred P. Sloan Fellow. | |||||||||
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| Issue or Number: | 7 | |||||||||
| DOI: | 10.1063/1.1734522 | |||||||||
| Record Number: | CaltechAUTHORS:20120829-105437675 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20120829-105437675 | |||||||||
| Official Citation: | Free Energy of Nonequilibrium Polarization Systems. III. Statistical Mechanics of Homogeneous and Electrode Systems R. A. Marcus J. Chem. Phys. 39, 1734 (1963); http://dx.doi.org/10.1063/1.1734522 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 33650 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 29 Aug 2012 18:13 | |||||||||
| Last Modified: | 09 Nov 2021 21:36 |
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