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The principle of microscopic reversibility

Tolman, Richard C. (1925) The principle of microscopic reversibility. Proceedings of the National Academy of Sciences of the United States of America, 11 (7). pp. 436-439. ISSN 0027-8424. PMCID PMC1086044. doi:10.1073/pnas.11.7.436.

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In recent years increasing use has been made of a new postulate which perhaps cannot yet be stated in its final form, but which requires in a general way in the case of a system in thermodynamic equilibrium not only that the total number of molecules leaving a given state in unit time shall on the average equal the number arriving in that state in unit time, but also that the number leaving by any particular path shall on the average be equal to the number arriving by the reverse of that particular path, thus excluding any cyclical maintenance of the equilibrium state.

Item Type:Article
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Additional Information:© 1925 by the National Academy of Sciences. Communicated May 19, 1925.
Issue or Number:7
PubMed Central ID:PMC1086044
Record Number:CaltechAUTHORS:TOLpnas25b
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:3385
Deposited By: Tony Diaz
Deposited On:05 Jun 2006
Last Modified:08 Nov 2021 19:55

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