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Energy Threshold for D+H_2→DH+H Reaction

Kuppermann, Aron and White, John M. (1966) Energy Threshold for D+H_2→DH+H Reaction. Journal of Chemical Physics, 44 (11). pp. 4352-4354. ISSN 0021-9606. doi:10.1063/1.1726631.

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We have been able to measure the threshold energy Eo for the reaction D+H_2→DH+H. The value obtained was (0.33±0.02) eV. Apparently, this is the first direct determination of a threshold energy for a reaction involving the formation and breaking of covalent bonds

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Additional Information:© 1966 American Institute of Physics. Received 3 March 1966. Online Publication Date: 18 May 2004. Work supported in part by the U.S. Atomic Energy Commission and the Petroleum Research Fund. Work performed while in residence at the California Institute of Technology in partial fulfillment of the requirements for the Ph.D. degree in chemistry from the University of Illinois, Urbana, Ill. Contribution No. 3035.
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Atomic Energy CommissionUNSPECIFIED
Petroleum Research FundUNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry3035
Issue or Number:11
Record Number:CaltechAUTHORS:20120905-111904894
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Official Citation:Energy Threshold for D+H2→DH+H Reaction Aron Kuppermann and John M. White J. Chem. Phys. 44, 4352 (1966);
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:33860
Deposited By: Ruth Sustaita
Deposited On:05 Sep 2012 18:47
Last Modified:09 Nov 2021 23:05

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