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2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of alpha-diazo-beta-ketoesters

Meyer, Michael E. and Ferreira, Eric M. and Stoltz, Brian M. (2006) 2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of alpha-diazo-beta-ketoesters. Chemical Communications, 2006 (12). pp. 1316-1318. ISSN 1359-7345. https://resolver.caltech.edu/CaltechAUTHORS:MEYcc06

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Abstract

The formation of various alpha-diazo acetoacetic esters can be obtained in a single transformation with good to excellent yields using readily available 2-diazoacetoacetic acid.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1039/b517719gDOIUNSPECIFIED
ORCID:
AuthorORCID
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© The Royal Society of Chemistry 2006 Received (in Bloomington, IN, USA) 13th December 2005, Accepted 27th January 2006. First published on the web 15th February 2006 The authors gratefully acknowledge the NSF (predoctoral fellowship for E.M.F.), Bristol-Myers Squibb (Graduate Fellowship in Synthetic Organic Chemistry to E.M.F.), AstraZeneca, Boehringer Ingelheim, Johnson & Johnson, Pfizer, Merck, Amgen, Research Corporation, Roche, the Dreyfus Foundation, and GlaxoSmithKline for generous funding. Electronic supplementary information (ESI) available: experimental details and characterization data for all compounds. See DOI: 10.1039/b517719g
Funders:
Funding AgencyGrant Number
NSF Predoctoral FellowshipUNSPECIFIED
Bristol-Myers SquibbUNSPECIFIED
AstraZenecaUNSPECIFIED
Boehringer-IngelheimUNSPECIFIED
Johnson and JohnsonUNSPECIFIED
PfizerUNSPECIFIED
MerckUNSPECIFIED
AmgenUNSPECIFIED
Research CorporationUNSPECIFIED
RocheUNSPECIFIED
Camille and Henry Dreyfus FoundationUNSPECIFIED
GlaxoSmithKlineUNSPECIFIED
Subject Keywords:C-H INSERTION; CARBONYL-COMPOUNDS; STEREOSELECTIVE-SYNTHESIS; CLAISEN REARRANGEMENT; WOLFF REARRANGEMENT; CYCLOADDITION; TRANSFORMATIONS; ACTIVATION; PRECURSORS; CATALYSTS
Issue or Number:12
Record Number:CaltechAUTHORS:MEYcc06
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:MEYcc06
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:3509
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:11 Jun 2006
Last Modified:02 Oct 2019 23:03

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