Meyer, Michael E. and Ferreira, Eric M. and Stoltz, Brian M. (2006) 2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of alpha-diazo-beta-ketoesters. Chemical Communications, 2006 (12). pp. 1316-1318. ISSN 1359-7345. doi:10.1039/b517719g. https://resolver.caltech.edu/CaltechAUTHORS:MEYcc06
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Abstract
The formation of various alpha-diazo acetoacetic esters can be obtained in a single transformation with good to excellent yields using readily available 2-diazoacetoacetic acid.
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| Additional Information: | © The Royal Society of Chemistry 2006 Received (in Bloomington, IN, USA) 13th December 2005, Accepted 27th January 2006. First published on the web 15th February 2006 The authors gratefully acknowledge the NSF (predoctoral fellowship for E.M.F.), Bristol-Myers Squibb (Graduate Fellowship in Synthetic Organic Chemistry to E.M.F.), AstraZeneca, Boehringer Ingelheim, Johnson & Johnson, Pfizer, Merck, Amgen, Research Corporation, Roche, the Dreyfus Foundation, and GlaxoSmithKline for generous funding. Electronic supplementary information (ESI) available: experimental details and characterization data for all compounds. See DOI: 10.1039/b517719g | ||||||||||||||||||||||||||
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| Subject Keywords: | C-H INSERTION; CARBONYL-COMPOUNDS; STEREOSELECTIVE-SYNTHESIS; CLAISEN REARRANGEMENT; WOLFF REARRANGEMENT; CYCLOADDITION; TRANSFORMATIONS; ACTIVATION; PRECURSORS; CATALYSTS | ||||||||||||||||||||||||||
| Issue or Number: | 12 | ||||||||||||||||||||||||||
| DOI: | 10.1039/b517719g | ||||||||||||||||||||||||||
| Record Number: | CaltechAUTHORS:MEYcc06 | ||||||||||||||||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:MEYcc06 | ||||||||||||||||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||||||||||||||||
| ID Code: | 3509 | ||||||||||||||||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||||||||||||||||
| Deposited By: | Archive Administrator | ||||||||||||||||||||||||||
| Deposited On: | 11 Jun 2006 | ||||||||||||||||||||||||||
| Last Modified: | 08 Nov 2021 19:56 |
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