CaltechAUTHORS
  A Caltech Library Service

Activator-Free Olefin Oligomerization and Isomerization Reactions Catalyzed by an Air- and Water-Tolerant Wacker Oxidation Intermediate

Winston, Matthew S. and Oblad, Paul F. and Labinger, Jay A. and Bercaw, John E. (2012) Activator-Free Olefin Oligomerization and Isomerization Reactions Catalyzed by an Air- and Water-Tolerant Wacker Oxidation Intermediate. Angewandte Chemie International Edition, 51 (39). pp. 9822-9824. ISSN 1433-7851. doi:10.1002/anie.201206215. https://resolver.caltech.edu/CaltechAUTHORS:20121107-102235374

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20121107-102235374

Abstract

A bench-stable, hydroxy-bridged α-diimine-Pd dimer can self-activate to an olefin oligomerization and isomerization catalyst in the presence of substrate (see scheme). A cationic Pd-hydride is generated principally through a Wacker oxidation of olefin to ketone, and with C_(4+) olefins, lesser amounts of allylic C-H activation, β-H transfer, and release of diene products are observed.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/anie.201206215 DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/anie.201206215/abstractPublisherArticle
ORCID:
AuthorORCID
Labinger, Jay A.0000-0002-1942-9232
Additional Information:© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: August 2, 2012. Published online: September 3, 2012. This work was supported by BP. We thank Dr. Glenn Sunley (BP) for helpful discussions, and Dr. Loi Do and Larry Henling for X-ray crystallographic analysis.
Funders:
Funding AgencyGrant Number
BPUNSPECIFIED
Subject Keywords:isomerization; oligomerization; oxidation; palladium; thermodynamics
Issue or Number:39
DOI:10.1002/anie.201206215
Record Number:CaltechAUTHORS:20121107-102235374
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20121107-102235374
Official Citation:Winston, M. S., Oblad, P. F., Labinger, J. A. and Bercaw, J. E. (2012), Activator-Free Olefin Oligomerization and Isomerization Reactions Catalyzed by an Air- and Water-Tolerant Wacker Oxidation Intermediate . Angew. Chem. Int. Ed., 51: 9822–9824. doi: 10.1002/anie.201206215
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:35325
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:07 Nov 2012 23:12
Last Modified:09 Nov 2021 23:14

Repository Staff Only: item control page