Winston, Matthew S. and Oblad, Paul F. and Labinger, Jay A. and Bercaw, John E. (2012) Activator-Free Olefin Oligomerization and Isomerization Reactions Catalyzed by an Air- and Water-Tolerant Wacker Oxidation Intermediate. Angewandte Chemie International Edition, 51 (39). pp. 9822-9824. ISSN 1433-7851. doi:10.1002/anie.201206215. https://resolver.caltech.edu/CaltechAUTHORS:20121107-102235374
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Abstract
A bench-stable, hydroxy-bridged α-diimine-Pd dimer can self-activate to an olefin oligomerization and isomerization catalyst in the presence of substrate (see scheme). A cationic Pd-hydride is generated principally through a Wacker oxidation of olefin to ketone, and with C_(4+) olefins, lesser amounts of allylic C-H activation, β-H transfer, and release of diene products are observed.
| Item Type: | Article | |||||||||
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| Additional Information: | © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: August 2, 2012. Published online: September 3, 2012. This work was supported by BP. We thank Dr. Glenn Sunley (BP) for helpful discussions, and Dr. Loi Do and Larry Henling for X-ray crystallographic analysis. | |||||||||
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| Subject Keywords: | isomerization; oligomerization; oxidation; palladium; thermodynamics | |||||||||
| Issue or Number: | 39 | |||||||||
| DOI: | 10.1002/anie.201206215 | |||||||||
| Record Number: | CaltechAUTHORS:20121107-102235374 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20121107-102235374 | |||||||||
| Official Citation: | Winston, M. S., Oblad, P. F., Labinger, J. A. and Bercaw, J. E. (2012), Activator-Free Olefin Oligomerization and Isomerization Reactions Catalyzed by an Air- and Water-Tolerant Wacker Oxidation Intermediate . Angew. Chem. Int. Ed., 51: 9822–9824. doi: 10.1002/anie.201206215 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 35325 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 07 Nov 2012 23:12 | |||||||||
| Last Modified: | 09 Nov 2021 23:14 |
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