CaltechAUTHORS
  A Caltech Library Service

Coriolis coupling as a source of non-RRKM effects in ozone molecule: Lifetime statistics of vibrationally excited ozone molecules

Kryvohuz, M. and Marcus, R. A. (2010) Coriolis coupling as a source of non-RRKM effects in ozone molecule: Lifetime statistics of vibrationally excited ozone molecules. Journal of Chemical Physics, 132 (22). Art. No. 224305. ISSN 0021-9606. https://resolver.caltech.edu/CaltechAUTHORS:20121129-095751831

[img]
Preview
PDF - Published Version
See Usage Policy.

657Kb
[img]
Preview
PDF - Erratum
See Usage Policy.

244Kb

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20121129-095751831

Abstract

A theory that describes the non-RRKM (non-Rice-Ramsperger-Kassel-Marcus) effects in the lifetime statistics of activated ozone molecules is derived. The non-RRKM effects are shown to originate due to the diffusive energy exchange between vibrational and rotational degrees of freedom in ozone molecule. The lifetime statistics is found to be intramolecular diffusion controlled at long times. The theoretical results are in good agreement with the direct MD simulations of lifetime statistics.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1063/1.3430514DOIUNSPECIFIED
http://jcp.aip.org/resource/1/jcpsa6/v132/i22/p224305_s1PublisherUNSPECIFIED
http://jcp.aip.org/resource/1/jcpsa6/v137/i15/p159902_s1Related ItemUNSPECIFIED
ORCID:
AuthorORCID
Marcus, R. A.0000-0001-6547-1469
Additional Information:© 2010 American Institute of Physics. Received 27 October 2009; accepted 27 April 2010; published online 8 June 2010. We are pleased to acknowledge the support of this research by the Glanville Fellowship to M.K. and by an NSF grant to R.A.M.
Funders:
Funding AgencyGrant Number
Glanville FellowshipUNSPECIFIED
NSFUNSPECIFIED
Subject Keywords:Coriolis force, excited states, intramolecular mechanics, ozone, rotational states, rotational-vibrational energy transfer, vibrational states
Issue or Number:22
Classification Code:PACS: 34.50.Ez; 33.20.Tp; 33.20.Sn
Record Number:CaltechAUTHORS:20121129-095751831
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20121129-095751831
Official Citation: Coriolis coupling as a source of non-RRKM effects in ozone molecule: Lifetime statistics of vibrationally excited ozone molecules M. Kryvohuz and R. A. Marcus, J. Chem. Phys. 132, 224305 (2010), DOI:10.1063/1.3430514
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:35725
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:29 Nov 2012 19:05
Last Modified:22 Nov 2019 09:58

Repository Staff Only: item control page