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Precisely Tunable Photonic Crystals From Rapidly Self-Assembling Brush Block Copolymer Blends

Miyake, Garret M. and Piunova, Victoria A. and Weitekamp, Raymond A. and Grubbs, Robert H. (2012) Precisely Tunable Photonic Crystals From Rapidly Self-Assembling Brush Block Copolymer Blends. Angewandte Chemie International Edition, 51 (45). pp. 11246-11248. ISSN 1433-7851. http://resolver.caltech.edu/CaltechAUTHORS:20121219-074712292

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Abstract

Colorful: Enabled by their reduced capacity for chain entanglement, high-molecular-weight brush block copolymers can rapidly self-assemble to photonic crystals. The blending of two polymers of different molecular weight can predictably modulate the sizes of the polymer domains, giving rise to a facile means of precision tuning of these photonic-band-gap materials.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/anie.201205743 DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/anie.201205743/abstractPublisherArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: July 18, 2012. Published online: September 13, 2012. This work was supported by a Dow Resnick Bridge Award. R.A.W. thanks the Resnick Sustainability Institute for a graduate fellowship.
Group:Resnick Sustainability Institute
Funders:
Funding AgencyGrant Number
Dow Resnick Bridge AwardUNSPECIFIED
Resnick Sustainability InstituteUNSPECIFIED
Subject Keywords:block copolymers; macromonomers; photonic crystals; ring-opening polymerization; self-assembly
Record Number:CaltechAUTHORS:20121219-074712292
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20121219-074712292
Official Citation:Miyake, G. M., Piunova, V. A., Weitekamp, R. A. and Grubbs, R. H. (2012), Precisely Tunable Photonic Crystals From Rapidly Self-Assembling Brush Block Copolymer Blends . Angew. Chem. Int. Ed., 51: 11246–11248. doi: 10.1002/anie.201205743
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:36035
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:19 Dec 2012 18:50
Last Modified:08 Dec 2016 00:16

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